(2R,4S)-2,4-Dimethyl-2-(4-trimethylstannanyl-butyl)-cyclopentanone | 142945-01-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子
• 英文名称: (2R,4S)-2,4-Dimethyl-2-(4-trimethylstannanyl-butyl)-cyclopentanone
• CAS: 142945-01-5
• 化学式: C₁₄H₂₈OSn
• 分子量: 331.086
• InChiKey: KLHAPPSIQONADE-QJDDDRAASA-N

物化性质

• 沸点：
  324.2±34.0 °C(Predicted)

反应信息

• 作为反应物：
  描述：

  (2R,4S)-2,4-Dimethyl-2-(4-trimethylstannanyl-butyl)-cyclopentanone 在 四氯化钛 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以94%的产率得到(1R,2R,4S)-2-But-3-enyl-2,4-dimethyl-cyclopentanol
  参考文献：
  名称：

  Lewis acid-induced reaction of silicon-containing stannyl ketones and its application to the synthesis of (+)-β-cuparenone

  摘要：

  Lewis acids activated only stannyl group in the silicon-containing stannyl keytones. The silyl group neither participated in the reaction directly, nor exerted any influences upon the reaction mode of the stannyl group. The reaction was applied for the synthesis of (+)-beta-cuparenone.

  DOI：

  10.1016/s0040-4020(01)92189-1
• 作为产物：
  描述：

  3-(trimethylstannyl)-3-(4-trimethylstannylbutyl)-5-methylcyclohexanone 在 三氟甲磺酸三甲基硅酯 作用下， 以 二氯甲烷 为溶剂， 反应 17.0h， 以20%的产率得到(2R,4S)-2,4-Dimethyl-2-(4-trimethylstannanyl-butyl)-cyclopentanone
  参考文献：
  名称：

  Lewis acid-induced reaction of silicon-containing stannyl ketones and its application to the synthesis of (+)-β-cuparenone

  摘要：

  Lewis acids activated only stannyl group in the silicon-containing stannyl keytones. The silyl group neither participated in the reaction directly, nor exerted any influences upon the reaction mode of the stannyl group. The reaction was applied for the synthesis of (+)-beta-cuparenone.

  DOI：

  10.1016/s0040-4020(01)92189-1