| 1006053-55-9

• 分子结构分类: 有机化合物 - 核苷、核苷酸和类似物 - 核苷和核苷酸类似物
• CAS: 1006053-55-9
• 化学式: C₃₇H₃₉N₅O₇
• 分子量: 665.746
• InChiKey: YIVCJJSXEPVZGY-AZWAZIRRSA-N

反应信息

• 作为反应物：
  描述：

  在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 14.0h， 以80%的产率得到[1S-(1α,2β,3α,4β)]-4-(2-acetylamino-6-benzyloxy-9H-purin-9-yl)-3-acetoxy-2-(benzyloxy)methyl-cyclopentanol
  参考文献：
  名称：

  Unusual β-Elimination of Carbocyclic Ketonucleosides Catalyzed by Silica Gel

  摘要：

  beta-elimination reactions occurred when carbocyclic ketonucleosides were treated with silica gel and alpha,beta-unsaturated ketonucleosides were obtained. The positions of ketone groups did not affect the occurrance of the elimination reaction. The yields of the reaction were influenced by the properties of leaving groups.

  DOI：

  10.1080/15257770601052273
• 作为产物：
  描述：

  [1S-(1α,2β,3α,5β)]-5-(2-amino-6-benzyloxy-9H-purin-9-yl)-3-(4-methoxybenzyl)oxy-2-(benzyloxy)methyl-cyclopentanol 、 乙酰氯 在 吡啶 、 4-二甲氨基吡啶 作用下， 以96%的产率得到
  参考文献：
  名称：

  Unusual β-Elimination of Carbocyclic Ketonucleosides Catalyzed by Silica Gel

  摘要：

  beta-elimination reactions occurred when carbocyclic ketonucleosides were treated with silica gel and alpha,beta-unsaturated ketonucleosides were obtained. The positions of ketone groups did not affect the occurrance of the elimination reaction. The yields of the reaction were influenced by the properties of leaving groups.

  DOI：

  10.1080/15257770601052273