| 1040750-63-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1040750-63-7
• 化学式: C₉₉H₆₂O₆
• 分子量: 1347.58
• InChiKey: QMOVDEYARWNAHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.59
• 重原子数：
  105.0
• 可旋转键数：
  31.0
• 环数：
  34.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  71.06
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  、 苄基叠氮 在 copper(ll) sulfate pentahydrate 、 sodium ascorbate 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 4.0h， 以80%的产率得到
  参考文献：
  名称：

  Synthesis of fullerene building blocks bearing alkyne or azide groups and their subsequent functionalization by the copper mediated Huisgen 1,3-dipolar cycloaddition

  摘要：

  C-60 derivatives bearing either terminal alkyne or azide functional groups have been prepared and used as building blocks under the copper mediated Huisgen 1,3-dipolar cycloaddition conditions. In general, the reactivity of C60 toward azides does not significantly compete with the cycloaddition leading to the desired 1,2,3-triazole derivatives and good yields can be obtained when fullerene derivatives with reasonable Solubility are used as starting materials. The electrochemical properties of the new fullerene derivatives have also been investigated by cyclic voltammetry (CV) and Osteryoung Square Wave Voltammetry (OSWV). (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.09.047
• 作为产物：
  描述：

  3-O-[(3,5-didodecoxyphenyl)methyl] 1-O-pent-4-ynyl propanedioate 、 足球烯 在 碘 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以31%的产率得到
  参考文献：
  名称：

  Synthesis of fullerene building blocks bearing alkyne or azide groups and their subsequent functionalization by the copper mediated Huisgen 1,3-dipolar cycloaddition

  摘要：

  C-60 derivatives bearing either terminal alkyne or azide functional groups have been prepared and used as building blocks under the copper mediated Huisgen 1,3-dipolar cycloaddition conditions. In general, the reactivity of C60 toward azides does not significantly compete with the cycloaddition leading to the desired 1,2,3-triazole derivatives and good yields can be obtained when fullerene derivatives with reasonable Solubility are used as starting materials. The electrochemical properties of the new fullerene derivatives have also been investigated by cyclic voltammetry (CV) and Osteryoung Square Wave Voltammetry (OSWV). (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.09.047

文献信息

• Click chemistry with fullerene derivatives
  作者：Julien Iehl、Rossimiriam Pereira de Freitas、Jean-François Nierengarten

  DOI：10.1016/j.tetlet.2008.04.064

  日期：2008.6

  C(60) derivatives bearing either terminal alkyne or azide functional groups have been prepared and used as building blocks under the copper-mediated Huisgen 1,3-dipolar cycloaddition conditions leading to 1,2,3-triazole derivatives. (C) 2008 Elsevier Ltd. All rights reserved.