(TTC)GePh | 1587717-12-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: (TTC)GePh
• 英文别名: (5,10,15-tritolylcorrole)Ge(phenyl)
• CAS: 1587717-12-1
• 化学式: C₄₆H₃₄GeN₄
• 分子量: 715.393
• InChiKey: CWRBLURUFGAQKQ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 苯基溴化镁 以 乙醚 、 二氯甲烷 为溶剂， 反应 0.17h， 以76%的产率得到(TTC)GePh
  参考文献：
  名称：

  Phenyl Derivative of Iron 5,10,15-Tritolylcorrole

  摘要：

  The phenyl iron complex of 5,10,15-tritolylcorrole was prepared by reaction of the starting chloro iron complex with phenylmagnesium bromide in dichloromethane. The organometallic complex was fully characterized by a combination of spectroscopic methods, X-ray crystallography, and density functional theory (DFT) calculations. All of these techniques support the description of the electronic structure of this phenyl iron derivative as a low-spin iron(IV) coordinated to a closed-shell corrolate trianion and to a phenyl monoanion. Complete assignments of the H-1 and C-13 NMR spectra of the phenyl iron derivative and the starting chloro iron complex were performed on the basis of the NMR spectra of the regioselectively beta-substituted bromo derivatives and the DFT calculations.

  DOI：

  10.1021/ic5003572