Fe(dipicolinate)(ethylenediamine)(H2O)2Cl | 180861-33-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Fe(dipicolinate)(ethylenediamine)(H2O)2Cl
• CAS: 180861-33-0
• 化学式: C₉H₁₃FeN₃O₅*Cl*H₂O
• 分子量: 352.535
• InChiKey: WFOJLYRCDJVPIG-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶-2,6-二甲酸 、 三氯化铁 、 乙二胺 以 乙醇 为溶剂， 生成 Fe(dipicolinate)(ethylenediamine)(H2O)2Cl
  参考文献：
  名称：

  Mixed ligand complexes of chromium(III) and iron(III): synthesis and evaluation as catalysts for oxidation of olefins

  摘要：

  The mixed ligand complexes Cr-III(dpa)(L)Cl and Fe-III(dpa)(L)(H2O)(x)Cl (where dpa = dipicolinic acid, L = ethylenediamine, 2,2-bipyridine or 1,10-phenanthroline, n = 1 or 2) were synthesized and characterized by elemental analysis and spectral, magnetic, conductance and electrochemical studies. The complexes were evaluated for their activity as catalysts for the epoxidation of olefins. The chromium complexes catalyzed epoxidation of olefins, viz., norbornene, cis-cyclooctene, styrene and cyclohexene with iodosylbenzene, to give corresponding epoxides. Oxidation of cyclohexene gave allylic oxidation products besides the epoxide. The iron complexes were nearly inactive as epoxidation catalysts under these conditions. Spectrophotometric and electrochemical measurements were used to deduce the cause of low catalytic activity.

  DOI：

  10.1016/1381-1169(95)00299-5