Cu(II)(3,3-dimethylglutarate)*H2O | 440634-62-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Cu(II)(3,3-dimethylglutarate)*H2O
• CAS: 440634-62-8
• 化学式: C₇H₁₀O₄*Cu*H₂O
• 分子量: 239.715
• InChiKey: UHCBUCCNOICQQZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.53
• 重原子数：
  13.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  111.76
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  Cu(II)(3,3-dimethylglutarate)*H2O 以 neat (no solvent, solid phase) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  摘要：

  Conditions for the preparation of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) 3,3-dimethylglutarates were investigated and their quantitative composition, solubility in water at 293 K and magnetic moments were determined. IR spectra and powder diffraction patterns of the complexes prepared with general formula MC7H10O4.nH(2)O (n=0-2) were recorded and their thermal decomposition in air were studied. During heating the hydrated complexes of Mn(II), Co(II), Ni(II) and Cu(II) are dehydrated in one step and next all the anhydrous complexes decompose to oxides directly (Mn, Co, Zn) or with intermediate formation free metal (Ni, Cu) or oxocarbonates (Cd). The carboxylate groups in the complexes studied are bidentate. The magnetic moments for the paramagnetic complexes of Mn(II), Co(II), Ni(II) and Cu(II) attain values 5.62, 5.25, 2.91 and 1.41 M.B., respectively.

  DOI：

  10.1023/a:1014300720524
• 作为产物：
  描述：

  copper(II) carbonate 、 3,3-二甲基戊二酸 、 水 以 水 为溶剂， 生成 Cu(II)(3,3-dimethylglutarate)*H2O
  参考文献：
  名称：

  摘要：

  Conditions for the preparation of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) 3,3-dimethylglutarates were investigated and their quantitative composition, solubility in water at 293 K and magnetic moments were determined. IR spectra and powder diffraction patterns of the complexes prepared with general formula MC7H10O4.nH(2)O (n=0-2) were recorded and their thermal decomposition in air were studied. During heating the hydrated complexes of Mn(II), Co(II), Ni(II) and Cu(II) are dehydrated in one step and next all the anhydrous complexes decompose to oxides directly (Mn, Co, Zn) or with intermediate formation free metal (Ni, Cu) or oxocarbonates (Cd). The carboxylate groups in the complexes studied are bidentate. The magnetic moments for the paramagnetic complexes of Mn(II), Co(II), Ni(II) and Cu(II) attain values 5.62, 5.25, 2.91 and 1.41 M.B., respectively.

  DOI：

  10.1023/a:1014300720524