methyl-bis(5-phenyltetrazol-1-yl)alumane | 211239-16-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: methyl-bis(5-phenyltetrazol-1-yl)alumane
• CAS: 211239-16-6
• 化学式: C₁₅H₁₃AlN₈
• 分子量: 332.303
• InChiKey: HHUNGDQITBPWPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.51
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  87.2
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  5-苯基四氮唑 、 三甲基铝 以 甲苯 为溶剂， 以94%的产率得到methyl-bis(5-phenyltetrazol-1-yl)alumane
  参考文献：
  名称：

  Syntheses and reactions of tetrazole-group 13 complexes

  摘要：

  The combination of 5-phenyl-1-H-tetrazole (tet) with AIR(3) in stoichiometries of 1-3 leads to the compounds [(tet)AIR(2)](n) R = Me (1), Et (2),Bu-i (3), [(tet)(2)AlMe](n) (4), and [(tet)(3)Al](n) (5). The addition of pyridine to 1 leads to a soluble compound with the formulation, [(tet)AlMe2-pyridine](n) (6). Likewise the addition of AlMe3 to 1 and 4 leads to the products [(tet)AlMe2-AlMe3](2) (7) and [(tet)(2)AlMe-AlMe3](n) (8). The compounds were characterized by standard techniques and, in the case of 7 by X-ray crystallography. Compounds 1, 4 and 5 were examined (unsuccessfully) as potential unimolecular precursors to aluminum nitride. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00057-6

文献信息

• New Precursors to Group 13 Nitrides
  作者：Michael Hill、Jolin Jegier、Miguel-Angel Munoz-Hernandez、Drew Rutherford、Amy Singer、David Atwood

  DOI：10.1080/10426509708545623

  日期：1997.1.1