1-(3-methylcymantrenyl)silatrane | 254977-23-6

• 英文名称: 1-(3-methylcymantrenyl)silatrane
• CAS: 254977-23-6
• 化学式: C₁₅H₁₈MnNO₆Si
• 分子量: 391.335
• InChiKey: UNBYBTLKNFGWGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  硅酸四乙酯 、 methylcyclopentadienyl manganese(I) tricarbonyl 、 三乙醇胺 在 BuLi 作用下， 以 not given 为溶剂， 生成 1-(3-methylcymantrenyl)silatrane
  参考文献：
  名称：

  Ferrocenylethenylsilatranes and a cymantrenylsilatrane

  摘要：

  The syntheses, properties and crystal structures of two isomeric ferrocenylethenylsilatranes and 1-(3-methylcymantrenyl)silatrane are reported. The organometallic moieties and the silatrane show little structural influence on each other. The Si-N distances remain in the expected range of 2.13-2.22 Angstrom, asserting the hypervalency of silicon. The electron-donating effect of the silatrane group is transmitted through the C-C double bond to ferrocene, as shown by the redox potentials. The first hyperpolarizability of the ferrocene derivatives was determined by hyper-Rayleigh scattering. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00440-4