| 1542141-77-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• CAS: 1542141-77-4
• 化学式: C₁₂H₁₁N₃*H₂O₄S
• 分子量: 295.319
• InChiKey: ORNMHCNGTMKXQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.81
• 重原子数：
  20.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  116.21
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  1-氰乙基-2-苯基咪唑 在 硫酸 作用下， 生成
  参考文献：
  名称：

  Protic Ionic Liquids and Salts as Versatile Carbon Precursors

  摘要：

  Instead of traditional polymer precursors and complex procedures, easily prepared and widely obtainable nitrogen-containing protic ionic liquids and salts were explored as novel, small-molecule precursors to prepare carbon materials (CMs) via direct carbonization without other treatments. Depending on the precursor structure, the resultant CMs can be readily obtained with a relative yield of up to 95.3%, a high specific surface area of up to 1380 m(2)/g, or a high N content of up to 11.1 wt%, as well as a high degree of graphitization and high conductivity (even higher than that of graphite). One of the carbons, which possesses a high surface area and a high content of pyridinic N, exhibits excellent electrocatalytic activity toward the oxygen reduction reaction in an alkaline medium, as revealed by an onset potential, half-wave potential, and kinetic current density comparable to those of commercial 20 wt% Pt/C. These low-cost and versatile precursors are expected to be important building blocks for CMs.

  DOI：

  10.1021/ja411981c