(1,4-bis(N-1-methylimidazol-2-yl-methyl)-1,4-diazacycloheptane)nickel(II) | 850732-46-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: (1,4-bis(N-1-methylimidazol-2-yl-methyl)-1,4-diazacycloheptane)nickel(II)
• CAS: 850732-46-6
• 化学式: C₁₅H₂₄N₆Ni
• 分子量: 347.086
• InChiKey: SSYFTHMEWLJWGH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Ni(1,4-bis(N-1-methylimidazol-2-yl-methyl)-1,4-diazacycloheptane)Cl](ClO4) 以 甲醇 为溶剂， 生成 (1,4-bis(N-1-methylimidazol-2-yl-methyl)-1,4-diazacycloheptane)nickel(II)
  参考文献：
  名称：

  Coordination chemistry of heterocycle-functionalized diazamesocycles: tuning the productive NiII complexes through altering the pendants of ligands

  摘要：

  In order to further understand the coordination chemistry of diazamesocyclic systems, a series of mononuclear Ni-II complexes with 1,4-diazacycloheptane (DACH) functionalized by additional imidazole or pyridine donor pendants, including [NiL1](ClO4)2 center dot H2O (1), [(NiLCl)-Cl-1](ClO4) (2), [(NiLCl)-Cl-2](ClO4) center dot CH3OH (3), [(NiLCl)-Cl-2][NiL2](ClO4)(3) (4) and [NiL3](ClO4)(2) (5), where L-1 = 1,4-bis(N-1-methylimidazol-2-yl-methyl)-1,4-diazacycloheptane, L-2= 1,4-bis(pyridyl-2-yl-methyl)-1,4-diazacycloheptane, and L-3= 1,4-bis-(imidazol-4-yl-methyl)-1,4-diazacycloheptane, have been prepared and characterized. A detailed study on the solid structures and solution spectra of these complexes indicates that tetradentate ligands L-1, L-2 and L-3 would lead to new Ni-II complexes with different coordination environments in the solid states and solution. The N-methyl substituted imidazole functionalized ligand L-1 forms green compound 2 and yellow product 1; while the pyridine functionalized ligand L-2 affords red product 4 and green complex 3; the ligand L-3 results in only one stable mononuclear Ni-II product 5. The solution behaviors of these interesting compounds were also investigated by UV-Vis technique. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.12.016