1-azidododeca-5,7-diyne | 1207336-84-2

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 1-azidododeca-5,7-diyne
• 英文别名: 1-Azidododeca-5,7-diyne
• CAS: 1207336-84-2
• 化学式: C₁₂H₁₇N₃
• 分子量: 203.287
• InChiKey: KCARJKALZFEYKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  14.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-bromododeca-5,7-diyne 在 叠氮基三甲基硅烷 、 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 96.0h， 以87%的产率得到1-azidododeca-5,7-diyne
  参考文献：
  名称：

  Synthesis and properties of diacetylene azides

  摘要：

  A three-stage method was developed for the synthesis of diacetylene azides from diacetylene alcohols prepared by Cadiot-Chodkiewicz reaction. By their bromination the corresponding diacetylene bromides were obtained whose azidation resulted in the target diacetylene azides. The attempt was performed to prepare azides of triacetylene series, but the low stability of the synthesized triacetylene alcohols prevented their conversion into the corresponding bromides.

  DOI：

  10.1134/s1070428009080028

文献信息

• Synthesis and properties of diacetylene azides
  作者：I. N. Domnin、L. A. Remizova

  DOI：10.1134/s1070428009080028

  日期：2009.8

  A three-stage method was developed for the synthesis of diacetylene azides from diacetylene alcohols prepared by Cadiot-Chodkiewicz reaction. By their bromination the corresponding diacetylene bromides were obtained whose azidation resulted in the target diacetylene azides. The attempt was performed to prepare azides of triacetylene series, but the low stability of the synthesized triacetylene alcohols prevented their conversion into the corresponding bromides.