(4R,5S,6R,7R)-4,5,6,7,8-Pentaacetoxy-3-oxo-octanoic acid methyl ester | 214067-94-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (4R,5S,6R,7R)-4,5,6,7,8-Pentaacetoxy-3-oxo-octanoic acid methyl ester
• CAS: 214067-94-4
• 化学式: C₁₉H₂₆O₁₃
• 分子量: 462.408
• InChiKey: CQTVEPKJOMUDBB-QXCFHYIPSA-N

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 (4R,5S,6R,7R)-4,5,6,7,8-Pentaacetoxy-3-oxo-octanoic acid methyl ester 在 aluminum oxide 作用下， 以 乙醚 、 丙酮 为溶剂， 以69.2%的产率得到(Z)-(4R,5S,6R,7R)-4,5,6,7,8-Pentaacetoxy-3-methoxy-oct-2-enoic acid methyl ester
  参考文献：
  名称：

  Synthesis and Reactions of Derivatives of 2-Deoxyoct-3-Ulosonic Acids

  摘要：

  Decarboalkoxylations of branched chain 2-deoxyoct-3-ulosonic acid derivatives furnished the unbranched 2-deoxyoct-3-ulosonic acid esters and nitriles, respectively. The O-methylation and halogenation of 2-deoxyoct-3-ulosonates are described.

  DOI：

  10.1080/07328309808001885
• 作为产物：
  描述：

  2-((2R,3S,4R,5R)-2,3,4,5,6-Pentaacetoxy-hexanoyl)-malonic acid benzyl ester methyl ester 在 palladium on activated charcoal 氢气 作用下， 以 乙酸乙酯 为溶剂， 以30.8%的产率得到(4R,5S,6R,7R)-4,5,6,7,8-Pentaacetoxy-3-oxo-octanoic acid methyl ester
  参考文献：
  名称：

  Synthesis and Reactions of Derivatives of 2-Deoxyoct-3-Ulosonic Acids

  摘要：

  Decarboalkoxylations of branched chain 2-deoxyoct-3-ulosonic acid derivatives furnished the unbranched 2-deoxyoct-3-ulosonic acid esters and nitriles, respectively. The O-methylation and halogenation of 2-deoxyoct-3-ulosonates are described.

  DOI：

  10.1080/07328309808001885