(2-iodophenyl)(2'-methoxyphenyl)methanone | 1446317-50-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-iodophenyl)(2'-methoxyphenyl)methanone
• 英文别名: (2-iodophenyl)(2’-methoxyphenyl)methanone；(2-Iodophenyl)-(2-methoxyphenyl)methanone
• CAS: 1446317-50-5
• 化学式: C₁₄H₁₁IO₂
• 分子量: 338.145
• InChiKey: YDEMVCLEEBZYMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2-iodophenyl)(2'-methoxyphenyl)methanone 在 bis-triphenylphosphine-palladium(II) chloride 、 三溴化硼 、 caesium carbonate 作用下， 以 二氯甲烷 、 N,N-二甲基乙酰胺 为溶剂， -78.0~150.0 ℃ 、2.0 MPa 条件下， 反应 1.58h， 生成 1-羟基-9-芴酮
  参考文献：
  名称：

  微波辅助分子内钯介导的邻碘二苯甲酮环化甲氧基芴9-酮

  摘要：

  摘要 微波 (MW) 辐照是在热条件下需要较长反应时间的有机反应中的有效工具。在此，取代的 2-碘二苯甲酮通过碳酸铯和双（三苯基膦）氯化钯 (II) 在微波照射下在 30-45 分钟内以 56-92% 的产率转化为取代的 fluoren-9-ones。观察到高产率产物的反应时间显着减少。分离产物在( 1 H/ 13 CNMR)和相关光谱的基础上得到了强调。

  DOI：

  10.1080/00397911.2022.2095210
• 作为产物：
  描述：

  (2-aminophenyl)(2-methoxyphenyl)methanone 在 溶剂黄146 、 1-硝基戊烷 、 potassium iodide 作用下， 以 水 为溶剂， 反应 4.0h， 以69%的产率得到(2-iodophenyl)(2'-methoxyphenyl)methanone
  参考文献：
  名称：

  微波辅助分子内钯介导的邻碘二苯甲酮环化甲氧基芴9-酮

  摘要：

  摘要 微波 (MW) 辐照是在热条件下需要较长反应时间的有机反应中的有效工具。在此，取代的 2-碘二苯甲酮通过碳酸铯和双（三苯基膦）氯化钯 (II) 在微波照射下在 30-45 分钟内以 56-92% 的产率转化为取代的 fluoren-9-ones。观察到高产率产物的反应时间显着减少。分离产物在( 1 H/ 13 CNMR)和相关光谱的基础上得到了强调。

  DOI：

  10.1080/00397911.2022.2095210

文献信息

• COMPOUND, RESIN, AND METHOD FOR PURIFYING SAME, UNDERLAYER FILM FORMATION MATERIAL FOR LITHOGRAPHY, UNDERLAYER FILM FORMING COMPOSITION, AND UNDERLAYER FILM, AND METHOD FOR FORMING RESIST PATTERN AND METHOD FOR FORMING CIRCUIT PATTERN
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3279179A1

  公开（公告）日：2018-02-07

  The present invention provides a compound represented by following formula (1), wherein R1 represents a 2n-valent group having 1 to 30 carbon atoms, each of R2 to R5 independently represents a straight, branched or cyclic alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkoxy group having 1 to 30 carbon atoms, a halogen atom, a thiol group or a hydroxyl group, provided that at least one selected from R1 to R5 represents a group including an iodine atom and at least one R4 and/or at least one R5 represent/represents one or more selected from the group consisting of a hydroxyl group and a thiol group, each of m2 and m3 independently represents an integer of 0 to 8, each of m4 and m5 independently represents an integer of 0 to 9, provided that m4 and m5 do not represent 0 at the same time, n represents an integer of 1 to 4, and each of p2 to p5 independently represents an integer of 0 to 2.

  本发明提供了由下式（1）代表的化合物、 其中 R1 代表具有 1 至 30 个碳原子的 2n 价基团，R2 至 R5 各自独立地代表具有 1 至 10 个碳原子的直链、支链或环状烷基、具有 6 至 10 个碳原子的芳基、具有 2 至 10 个碳原子的烯基、具有 1 至 30 个碳原子的烷氧基、卤素原子、硫醇基或羟基、m2和m3各自独立地代表0至8的整数，m4和m5各自独立地代表0至9的整数，但m4和m5不能同时代表0，n代表1至4的整数，p2至p5各自独立地代表0至2的整数。
• Compound, resin, and purification method thereof, material for forming underlayer film for lithography, composition for forming underlayer film, and underlayer film, as well as resist pattern forming method and circuit pattern forming method
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US10747112B2

  公开（公告）日：2020-08-18

  The present invention provides a compound represented by following formula (1), wherein R1 represents a 2n-valent group having 1 to 30 carbon atoms, each of R2 to R5 independently represents a straight, branched or cyclic alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkoxy group having 1 to 30 carbon atoms, a halogen atom, a thiol group or a hydroxyl group, provided that at least one selected from R1 to R5 represents a group including an iodine atom and at least one R4 and/or at least one R5 represent/represents one or more selected from the group consisting of a hydroxyl group and a thiol group, each of m2 and m3 independently represents an integer of 0 to 8, each of m4 and m5 independently represents an integer of 0 to 9, provided that m4 and m5 do not represent 0 at the same time, n represents an integer of 1 to 4, and each of p2 to p5 independently represents an integer of 0 to 2.

  本发明提供了由下式（1）代表的化合物、 其中 R1 代表具有 1 至 30 个碳原子的 2n 价基团，R2 至 R5 各自独立地代表具有 1 至 10 个碳原子的直链、支链或环状烷基、具有 6 至 10 个碳原子的芳基、具有 2 至 10 个碳原子的烯基、具有 1 至 30 个碳原子的烷氧基、卤素原子、硫醇基或羟基、m2和m3各自独立地代表0至8的整数，m4和m5各自独立地代表0至9的整数，但m4和m5不能同时代表0，n代表1至4的整数，p2至p5各自独立地代表0至2的整数。
• Cu(I)-catalyzed intramolecular cyclizations of substituted 2-iodobenzophenones under thermal and microwave conditions
  作者：Reda A. Haggam

  DOI：10.1016/j.tet.2013.05.077

  日期：2013.8

  Novel, easy-to-perform and practical intramolecular Cu(I)-catalyzed cyclizations of substituted 2-iodobenzophenones under thermal and microwave conditions are reported. The isolated cyclized products under microwave conditions are obtained with high yields and with short reaction times offering a valuable and reliable alternative to other protocols for the synthesis of fluorene analogues. (C) 2013 Elsevier Ltd. All rights reserved.
• COMPOUND, RESIN, AND PURIFICATION METHOD THEREOF, MATERIAL FOR FORMING UNDERLAYER FILM FOR LITHOGRAPHY, COMPOSITION FOR FORMING UNDERLAYER FILM , AND UNDERLAYER FILM, AS WELL AS RESIST PATTERN FORMING METHOD AND CIRCUIT PATTERN FORMING METHOD.
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP3279179B1

  公开（公告）日：2019-12-18
• COMPOUND, RESIN, AND PURIFICATION METHOD THEREOF, MATERIAL FOR FORMING UNDERLAYER FILM FOR LITHOGRAPHY, COMPOSITION FOR FORMING UNDERLAYER FILM, AND UNDERLAYER FILM, AS WELL AS RESIST PATTERN FORMING METHOD AND CIRCUIT PATTERN FORMING METHOD
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：US20180095368A1

  公开（公告）日：2018-04-05

  The present invention provides a compound represented by following formula (1), wherein R 1 represents a 2n-valent group having 1 to 30 carbon atoms, each of R 2 to R 5 independently represents a straight, branched or cyclic alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkoxy group having 1 to 30 carbon atoms, a halogen atom, a thiol group or a hydroxyl group, provided that at least one selected from R 1 to R 5 represents a group including an iodine atom and at least one R 4 and/or at least one R 5 represent/represents one or more selected from the group consisting of a hydroxyl group and a thiol group, each of m 2 and m 3 independently represents an integer of 0 to 8, each of m 4 and m 5 independently represents an integer of 0 to 9, provided that m 4 and m 5 do not represent 0 at the same time, n represents an integer of 1 to 4, and each of p 2 to p 5 independently represents an integer of 0 to 2.