9,10,20,21,22,23-hexahydro-5H,12H-dibenzo[b,n][1,7,10,16,4,13]tetrathiadiazacycloicosine-6,13(7H,14H)-dione | 1227404-54-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 9,10,20,21,22,23-hexahydro-5H,12H-dibenzo[b,n][1,7,10,16,4,13]tetrathiadiazacycloicosine-6,13(7H,14H)-dione
• 英文别名: 2,7,17,20-Tetrathia-14,23-diazatricyclo[22.4.0.08,13]octacosa-1(28),8,10,12,24,26-hexaene-15,22-dione；2,7,17,20-tetrathia-14,23-diazatricyclo[22.4.0.08,13]octacosa-1(28),8,10,12,24,26-hexaene-15,22-dione
• CAS: 1227404-54-7
• 化学式: C₂₂H₂₆N₂O₂S₄
• 分子量: 478.725
• InChiKey: XSGCMCUULOYSQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  159
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,4-bis[(2-chloroacetamido)thiophenoxy]butane 、 1,2-乙二硫醇 在 sodium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.5h， 以91.2%的产率得到9,10,20,21,22,23-hexahydro-5H,12H-dibenzo[b,n][1,7,10,16,4,13]tetrathiadiazacycloicosine-6,13(7H,14H)-dione
  参考文献：
  名称：

  A comparative study of four 20-membered N2S4-crown ethers as ionophores for polymeric membrane silver selective electrodes

  摘要：

  Four 20-membered N2S4-monoazathiacrown ethers have been synthesized and explored as neutral ionophores for Ag+-selective electrodes. Potentiometric responses reveal that the flexibility of the ligands has great effect on the selectivity and sensitivity to Ag+ ions. The electrode based on ionophore 9,10,20,25-tetrahydro-5H,12H-tribenzo[b,n,r][1,7,10,16,4,13]tetrathiadiaza cycloicosine 6,13-(7H,14H)-dione (C) with 2-nitrophenyl octyl ether (o-NPOE) as solvent in a poly(vinyl chloride) (PVC) membrane matrix shows a measuring range of 1.0 x 10(-6) to 1.0 x 10(-3) mol/L with a Nernstian slope of 54.9 +/- 0.3 mV/decade. This electrode has high selectivity for Ag+ with negligible interference from many other cations and can be used in a wide pH range of 3.6-9.2. (C) 2009 Wei Qin. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2009.11.028

文献信息

• A comparative study of four 20-membered N2S4-crown ethers as ionophores for polymeric membrane silver selective electrodes
  作者：Jun Zhang、Shun Yang Yu、Tan Ji Yin、Xue Feng Hu、Wei Qin

  DOI：10.1016/j.cclet.2009.11.028

  日期：2010.4

  Four 20-membered N2S4-monoazathiacrown ethers have been synthesized and explored as neutral ionophores for Ag+-selective electrodes. Potentiometric responses reveal that the flexibility of the ligands has great effect on the selectivity and sensitivity to Ag+ ions. The electrode based on ionophore 9,10,20,25-tetrahydro-5H,12H-tribenzo[b,n,r][1,7,10,16,4,13]tetrathiadiaza cycloicosine 6,13-(7H,14H)-dione (C) with 2-nitrophenyl octyl ether (o-NPOE) as solvent in a poly(vinyl chloride) (PVC) membrane matrix shows a measuring range of 1.0 x 10(-6) to 1.0 x 10(-3) mol/L with a Nernstian slope of 54.9 +/- 0.3 mV/decade. This electrode has high selectivity for Ag+ with negligible interference from many other cations and can be used in a wide pH range of 3.6-9.2. (C) 2009 Wei Qin. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.