3-methyl-bicyclo[2.2.2]oct-5-ene-2-carbaldehyde | 2958-78-3

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 3-methyl-bicyclo[2.2.2]oct-5-ene-2-carbaldehyde
• 英文别名: 3-Methyl-bicyclo[2.2.2]oct-5-en-2-carbaldehyd；2-Formyl-3-methyl-bicyclo<2.2.2>octen-(5)；2-Formyl-3-methyl-bicyclo<2.2.2>oct-5-en；3-Methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde
• CAS: 2958-78-3
• 化学式: C₁₀H₁₄O
• 分子量: 150.221
• InChiKey: WQFNJPGOBMXXIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-methyl-bicyclo[2.2.2]oct-5-ene-2-carbaldehyde 在 乙醇 、 一水合肼 作用下， 生成 endo-2,3-dimethylbicyclo<2.2.2>oct-5-ene
  参考文献：
  名称：

  Kasansski; Sswirsskaja, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 2588

  摘要：

  DOI：
• 作为产物：
  描述：

  巴豆醛 、 1,3-环己二烯 生成 3-methyl-bicyclo[2.2.2]oct-5-ene-2-carbaldehyde
  参考文献：
  名称：

  Kasanski; Swirskaja, Zhurnal Obshchei Khimii, 1959, vol. 29, p. 2976

  摘要：

  DOI：

文献信息

• STRONGLY LEWIS ACIDIC METAL-ORGANIC FRAMEWORKS FOR CONTINUOUS FLOW CATALYSIS
  申请人：The University of Chicago

  公开号：US20210053042A1

  公开（公告）日：2021-02-25

  Lewis acidic metal-organic framework (MOF) materials comprising triflate-coordinated metal nodes are described. The materials can be used as heterogenous catalysts in a wide range of organic group transformations, including Diels-Alder reactions, epoxide-ring opening reactions, Friedel-Crafts acylation reactions and alkene hydroalkoxylation reactions. The MOFs can also be prepared with metallated organic bridging ligands to provide heterogenous catalysts for tandem reactions and/or prepared as composites with support particles for use in columns of continuous flow reactor systems. Methods of preparing and using the MOF materials and their composites are also described.

  描述了包含三氟甲磺酸盐配位金属节点的Lewis酸性金属有机框架（MOF）材料。这些材料可用作广泛范围的有机基团转化中的杂质催化剂，包括Diels-Alder反应、环氧化物开环反应、Friedel-Crafts酰化反应和烯烃水解烷氧基化反应。这些MOF还可以通过金属化有机桥联配体制备，以提供串联反应的杂质催化剂和/或与支撑颗粒制备为复合材料，用于连续流反应器系统的柱中。还描述了制备和使用MOF材料及其复合材料的方法。
• PROCESS FOR PRODUCING CYCLIC UNSATURATED ALDEHYDES
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0860421A1

  公开（公告）日：1998-08-26

  A process for producing a cyclic unsaturated aldehyde is herein disclosed which comprises the step of reacting a cyclic conjugated diene compound with an aldehyde represented by the general formula (I)         R-CH=CH-CHO     (I)    wherein R is an alkyl group having 1 to 3 carbon atoms, in the presence of a solid acid catalyst in accordance with the Diels-Alder reaction. According to the process of the present invention, the cyclic unsaturated aldehydes useful as the raw materials of traction oils and the like can efficiently and industrially advantageously be produced through the Diels-Alder reaction at a low cost without causing the corrosion of an apparatus and without requiring any treatment after the reaction.

  本文公开了一种生产环状不饱和醛的工艺，该工艺包括以下步骤：使环状共轭二烯化合物与通式 (I) 所代表的醛发生反应 R-CH=CH-CHO (I) 其中 R 是具有 1 至 3 个碳原子的烷基、 在固体酸催化剂存在下，按照 Diels-Alder 反应进行。 根据本发明的工艺，可通过 Diels-Alder 反应高效生产用作牵引油等原料的环状不饱和醛，且成本低廉，不会对设备造成腐蚀，反应后无需进行任何处理。
• DE526168
  申请人：——

  公开号：——

  公开（公告）日：——
• Petit,F. et al., Bulletin de la Societe Chimique de France, 1972, p. 747 - 752
  作者：Petit,F. et al.

  DOI：——

  日期：——
• DE545398
  申请人：——

  公开号：——

  公开（公告）日：——