cis-[PdMe(O2COH)(N,N,N',N'-tetramethylethylenediamine)] | 691866-04-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: cis-[PdMe(O2COH)(N,N,N',N'-tetramethylethylenediamine)]
• 英文别名: carbanide;hydrogen carbonate;palladium(2+);N,N,N',N'-tetramethylethane-1,2-diamine
• CAS: 691866-04-3
• 化学式: C₈H₂₀N₂O₃Pd
• 分子量: 298.678
• InChiKey: FEHXCRGFBNGAJX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[PdMe(O2COH)(N,N,N',N'-tetramethylethylenediamine)] 、 水 以 丙酮 为溶剂， 生成 cis-[Pd(η2-carbonate)(N,N,N',N'-tetramethylethylenediamine)]*H2O
  参考文献：
  名称：

  Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes

  摘要：

  Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.10.027
• 作为产物：
  描述：

  (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) 、 二氧化碳 以 苯 为溶剂， 以52%的产率得到cis-[PdMe(O2COH)(N,N,N',N'-tetramethylethylenediamine)]
  参考文献：
  名称：

  Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes

  摘要：

  Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.10.027