p-tetracarboxycalix[4]arene tetradodecyl ether | 908010-95-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: p-tetracarboxycalix[4]arene tetradodecyl ether
• 英文别名: 25,26,27,28-Tetradodecoxypentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-5,11,17,23-tetracarboxylic acid；25,26,27,28-tetradodecoxypentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-5,11,17,23-tetracarboxylic acid
• CAS: 908010-95-7
• 化学式: C₈₀H₁₂₀O₁₂
• 分子量: 1273.83
• InChiKey: RHFXMWNOIMLKCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  28
• 重原子数：
  92
• 可旋转键数：
  52
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  186
• 氢给体数：
  4
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  25,26,27,28-tetradodecyl-calix[4]arene 在 sodium chlorite 、 氨基磺酸 、 三氟乙酸 作用下， 以 氯仿 、 水 、 丙酮 为溶剂， 反应 24.0h， 生成 p-tetracarboxycalix[4]arene tetradodecyl ether
  参考文献：
  名称：

  Self-Organized Honeycomb-Patterned Microporous Polystyrene Thin Films Fabricated by Calix[4]arene Derivatives

  摘要：

  Calix[4]arene derivatives bearing carboxyl groups at the upper rim and alkyl groups at the lower rim were synthesized. Micrometer-size porous honeycomb-patterned thin films were prepared by evaporating chloroform solution of polystyrene containing the calixarene derivatives under high humidity. These films were coated on gold electrodes of QCM, and the high-frequency changes were observed to detect volatile organic compounds such as dichlorobenzene.

  DOI：

  10.1021/la100434b

文献信息

• Self-Organized Honeycomb-Patterned Microporous Polystyrene Thin Films Fabricated by Calix[4]arene Derivatives
  作者：Eisaku Nomura、Asao Hosoda、Masafumi Takagaki、Hajime Mori、Yasuhito Miyake、Motonari Shibakami、Hisaji Taniguchi

  DOI：10.1021/la100434b

  日期：2010.6.15

  Calix[4]arene derivatives bearing carboxyl groups at the upper rim and alkyl groups at the lower rim were synthesized. Micrometer-size porous honeycomb-patterned thin films were prepared by evaporating chloroform solution of polystyrene containing the calixarene derivatives under high humidity. These films were coated on gold electrodes of QCM, and the high-frequency changes were observed to detect volatile organic compounds such as dichlorobenzene.