| 1568662-60-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• CAS: 1568662-60-1
• 化学式: C₂₆H₃₂N₁₀O₉
• 分子量: 628.602
• InChiKey: XYSSNDUVLBDXCQ-WKHIFJLJSA-N

反应信息

• 作为反应物：
  描述：

  、 6,12,18,39-Tetrakis(prop-2-ynoxy)-25,29,33,37-tetra(undecyl)-2,4,8,10,14,16,20,22-octaoxanonacyclo[21.15.1.124,38.05,36.07,34.011,32.013,30.017,28.019,26]tetraconta-1(39),5,7(34),11,13(30),17(28),18,23,26,31,35,38(40)-dodecaene 在 copper(ll) sulfate pentahydrate 、 caesium ascorbate 作用下， 以 水 、 二甲基亚砜 为溶剂， 反应 24.0h， 以37%的产率得到
  参考文献：
  名称：

  Self-assembly of a thymine quartet and quadruplex via an organic template

  摘要：

  The synthesis of two hydrophobic cavitands bearing four (1) and eight (2) thymidine residues covalently linked with triazole moieties is reported. Spectral evidence indicates the adoption of a hydrogen-bonded T-quartet assembly by 1 in chloroform at low temperature and a pi-stacked quadruplex by 2 in DMSO under ambient conditions. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.058
• 作为产物：
  描述：

  在 sodium azide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以36%的产率得到
  参考文献：
  名称：

  Self-assembly of a thymine quartet and quadruplex via an organic template

  摘要：

  The synthesis of two hydrophobic cavitands bearing four (1) and eight (2) thymidine residues covalently linked with triazole moieties is reported. Spectral evidence indicates the adoption of a hydrogen-bonded T-quartet assembly by 1 in chloroform at low temperature and a pi-stacked quadruplex by 2 in DMSO under ambient conditions. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.01.058