N-[[4-[3,3,4,4,5,5-hexafluoro-2-(5-methoxy-1,2-dimethylindol-3-yl)cyclopenten-1-yl]-5-methylthiophen-2-yl]methyl]-1-phenylmethanamine | 1417901-20-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: N-[[4-[3,3,4,4,5,5-hexafluoro-2-(5-methoxy-1,2-dimethylindol-3-yl)cyclopenten-1-yl]-5-methylthiophen-2-yl]methyl]-1-phenylmethanamine
• CAS: 1417901-20-2
• 化学式: C₂₉H₂₆F₆N₂OS
• 分子量: 564.595
• InChiKey: GJKFDLHOUGBJQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  39
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  N-[[4-[3,3,4,4,5,5-hexafluoro-2-(5-methoxy-1,2-dimethylindol-3-yl)cyclopenten-1-yl]-5-methylthiophen-2-yl]methyl]-1-phenylmethanamine 在 盐酸 、 ammonium hexafluorophosphate 作用下， 以 甲醇 、 水 为溶剂， 生成 Benzyl-[[4-[3,3,4,4,5,5-hexafluoro-2-(5-methoxy-1,2-dimethylindol-3-yl)cyclopenten-1-yl]-5-methylthiophen-2-yl]methyl]azanium;chloride
  参考文献：
  名称：

  Dual-Stimulus Luminescent Lanthanide Molecular Switch Based on an Unsymmetrical Diarylperfluorocyclopentene

  摘要：

  A [2]pseudorotaxane formed from an unsymmetrical diarylperfluorocyclopentene (1) and a Eu3+ complex of terpyridinyldibenzo-24-crown-8 (2) revealed excellent reversible lanthanide luminescence switching behavior dual-modulated by host guest and optical stimuli.

  DOI：

  10.1021/ja4018804
• 作为产物：
  描述：

  全氟环戊烯 在 正丁基锂 、 三乙胺 作用下， 以 四氢呋喃 、 甲醇 、 正己烷 为溶剂， 反应 108.0h， 生成 N-[[4-[3,3,4,4,5,5-hexafluoro-2-(5-methoxy-1,2-dimethylindol-3-yl)cyclopenten-1-yl]-5-methylthiophen-2-yl]methyl]-1-phenylmethanamine
  参考文献：
  名称：

  Dual-Stimulus Luminescent Lanthanide Molecular Switch Based on an Unsymmetrical Diarylperfluorocyclopentene

  摘要：

  A [2]pseudorotaxane formed from an unsymmetrical diarylperfluorocyclopentene (1) and a Eu3+ complex of terpyridinyldibenzo-24-crown-8 (2) revealed excellent reversible lanthanide luminescence switching behavior dual-modulated by host guest and optical stimuli.

  DOI：

  10.1021/ja4018804

文献信息

• Dual-Stimulus Luminescent Lanthanide Molecular Switch Based on an Unsymmetrical Diarylperfluorocyclopentene
  作者：Hong-Bo Cheng、Heng-Yi Zhang、Yu Liu

  DOI：10.1021/ja4018804

  日期：2013.7.17

  A [2]pseudorotaxane formed from an unsymmetrical diarylperfluorocyclopentene (1) and a Eu3+ complex of terpyridinyldibenzo-24-crown-8 (2) revealed excellent reversible lanthanide luminescence switching behavior dual-modulated by host guest and optical stimuli.