3-bromo-9,9-dibutylfluorene | 1246026-60-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 3-bromo-9,9-dibutylfluorene
• 英文别名: 3-Bromo-9,9-dibutylfluorene
• CAS: 1246026-60-7
• 化学式: C₂₁H₂₅Br
• 分子量: 357.334
• InChiKey: XLMONCZHZHUMLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-bromo-9,9-dibutylfluorene 、 N,N-二甲基甲酰胺 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 以66%的产率得到9,9-dibutylfluorene-3-carbaldehyde
  参考文献：
  名称：

  Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues

  摘要：

  Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone. McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.07.064
• 作为产物：
  描述：

  正溴丁烷 、 3-溴-9H-芴 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以64.6%的产率得到3-bromo-9,9-dibutylfluorene
  参考文献：
  名称：

  Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues

  摘要：

  Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone. McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.07.064

文献信息

• BORENTHALTENDE VERBINDUNGEN
  申请人：Merck Patent GmbH

  公开号：EP3904361A2

  公开（公告）日：2021-11-03

  Die vorliegende Erfindung betrifft borenthaltende Verbindungen mit bicyclischen Struktureinheiten sowie elektronische Vorrichtungen, insbesondere organische Elektrolumineszenzvorrichtungen, enthaltend diese Verbindungen.

  本发明涉及具有双环结构单元的含硼化合物和含有这些化合物的电子器件，特别是有机电致发光器件。
• BORON-CONTAINING COMPOUNDS
  申请人：MERCK PATENT GMBH

  公开号：US20160248015A1

  公开（公告）日：2016-08-25

  The invention relates to boron-containing compounds with bicyclic structural units and to electronic devices, in particular organic electroluminescent devices, containing said compounds
• [DE] BORENTHALTENDE VERBINDUNGEN<br/>[EN] BORON-CONTAINING COMPOUNDS<br/>[FR] COMPOSÉS CONTENANT DU BORE
  申请人：MERCK PATENT GMBH

  公开号：WO2015049030A2

  公开（公告）日：2015-04-09

  Die vorliegende Erfindung betrifft borenthaltende Verbindungen mit bicyclischen Struktureinheiten sowie elektronische Vorrichtungen, insbesondere organische Elektrolumineszenzvorrichtungen, enthaltend diese Verbindungen.
• Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues
  作者：Yabin Song、Wei Xu、Daoben Zhu

  DOI：10.1016/j.tetlet.2010.07.064

  日期：2010.9

  Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone. McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared. (C) 2010 Elsevier Ltd. All rights reserved.