3,6-Di(carbazol-9-yl)-9-[6-[6-[3,6-di(carbazol-9-yl)carbazol-9-yl]-9-(2-ethylhexyl)carbazol-3-yl]-9-(2-ethylhexyl)carbazol-3-yl]carbazole | 1334631-56-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-Di(carbazol-9-yl)-9-[6-[6-[3,6-di(carbazol-9-yl)carbazol-9-yl]-9-(2-ethylhexyl)carbazol-3-yl]-9-(2-ethylhexyl)carbazol-3-yl]carbazole
• 英文别名: 3,6-di(carbazol-9-yl)-9-[6-[6-[3,6-di(carbazol-9-yl)carbazol-9-yl]-9-(2-ethylhexyl)carbazol-3-yl]-9-(2-ethylhexyl)carbazol-3-yl]carbazole
• CAS: 1334631-56-9
• 化学式: C₁₁₂H₉₀N₈
• 分子量: 1548.0
• InChiKey: VYVYSPXOZJFEBI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  31
• 重原子数：
  120
• 可旋转键数：
  19
• 环数：
  24.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  39.4
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  、 咔唑 在 铜 、 potassium carbonate 作用下， 以 硝基苯 为溶剂， 反应 40.0h， 以58%的产率得到3,6-Di(carbazol-9-yl)-9-[6-[6-[3,6-di(carbazol-9-yl)carbazol-9-yl]-9-(2-ethylhexyl)carbazol-3-yl]-9-(2-ethylhexyl)carbazol-3-yl]carbazole
  参考文献：
  名称：

  Synthesis and characterization of high Tg carbazole-based amorphous hole-transporting materials for organic light-emitting devices

  摘要：

  Novel hole-transporting materials based on carbazole dendrimers, namely G1CBC and G2CBC were synthesized and characterized. They are thermally stable with high glass transition temperatures (T-g) up to 245 degrees C and exhibit chemically-stable redox processes. Double-layer green OLEDs using these materials as the hole-transporting layer (HTL) with the device configuration of ITO/HTL/Alq3/LiF:Al emit brightly (lambda(em) 522-534 nm) from the Alq3 layer with a maximum luminance and low turn-on voltage of 15,890 cd/m(2) and 3.0 V. respectively. Their ability as HTLs in terms of device performance is comparable to the common hole-transporter N,N'-diphenyl-N,N'-bis(1-naphthyl)-(1,1'-biphenyl)-4,4'-diamine (NPB), however their thermal properties were far greater than both NPB and N,N'-bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine (TPD). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.07.002

文献信息

• Synthesis and characterization of high Tg carbazole-based amorphous hole-transporting materials for organic light-emitting devices
  作者：A-Monrat Thaengthong、Sayant Saengsuwan、Siriporn Jungsuttiwong、Tinnagon Keawin、Taweesak Sudyoadsuk、Vinich Promarak

  DOI：10.1016/j.tetlet.2011.07.002

  日期：2011.9

  Novel hole-transporting materials based on carbazole dendrimers, namely G1CBC and G2CBC were synthesized and characterized. They are thermally stable with high glass transition temperatures (T-g) up to 245 degrees C and exhibit chemically-stable redox processes. Double-layer green OLEDs using these materials as the hole-transporting layer (HTL) with the device configuration of ITO/HTL/Alq3/LiF:Al emit brightly (lambda(em) 522-534 nm) from the Alq3 layer with a maximum luminance and low turn-on voltage of 15,890 cd/m(2) and 3.0 V. respectively. Their ability as HTLs in terms of device performance is comparable to the common hole-transporter N,N'-diphenyl-N,N'-bis(1-naphthyl)-(1,1'-biphenyl)-4,4'-diamine (NPB), however their thermal properties were far greater than both NPB and N,N'-bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine (TPD). (C) 2011 Elsevier Ltd. All rights reserved.