1,1,1,3,3,3-Hexamethyl-2-(2,4,6-triisopropyl-phenyl)-2-(2,4,6-trimethyl-phenyl)-trisilane | 149209-42-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1,1,3,3,3-Hexamethyl-2-(2,4,6-triisopropyl-phenyl)-2-(2,4,6-trimethyl-phenyl)-trisilane
• 英文别名: Trimethyl-[(2,4,6-trimethylphenyl)-trimethylsilyl-[2,4,6-tri(propan-2-yl)phenyl]silyl]silane；trimethyl-[(2,4,6-trimethylphenyl)-trimethylsilyl-[2,4,6-tri(propan-2-yl)phenyl]silyl]silane
• CAS: 149209-42-7
• 化学式: C₃₀H₅₂Si₃
• 分子量: 496.999
• InChiKey: FHHPNRUBANIBCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.38
• 重原子数：
  33
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,1,1,3,3,3-Hexamethyl-2-(2,4,6-triisopropyl-phenyl)-2-(2,4,6-trimethyl-phenyl)-trisilane 以 正戊烷 为溶剂， 反应 48.0h， 生成 e-1,2-Bis(2,4,6-triisopropylphenyl)-1,2-dimesityldisilene
  参考文献：
  名称：

  Linear 2,2-diaryl-substituted trisilanes: Structure and photolysis to disilenes

  摘要：

  Synthesis of the new disilene, E/Z-IsMesSi=SiIsMes (1) is reported; the isomer Is2Si=SiMes2 (2) was obtained by photolysis of a mixture of Mes2Si(SiMe3)2 (3) and Is2Si(SiMe3)2 (5). Isomerization of 1 half arrow right over half arrow left 2 does not take place up to 80-degrees-C. X-Ray crystal structures are reported for trisilanes 3, IsMesSi(SiMe3)2 (4), and 5.

  DOI：

  10.1016/0022-328x(93)80035-a
• 作为产物：
  描述：

  三甲基氯硅烷 、 Dichloro-(2,4,6-triisopropyl-phenyl)-(2,4,6-trimethyl-phenyl)-silane 在 lithium 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以79%的产率得到1,1,1,3,3,3-Hexamethyl-2-(2,4,6-triisopropyl-phenyl)-2-(2,4,6-trimethyl-phenyl)-trisilane
  参考文献：
  名称：

  Linear 2,2-diaryl-substituted trisilanes: Structure and photolysis to disilenes

  摘要：

  Synthesis of the new disilene, E/Z-IsMesSi=SiIsMes (1) is reported; the isomer Is2Si=SiMes2 (2) was obtained by photolysis of a mixture of Mes2Si(SiMe3)2 (3) and Is2Si(SiMe3)2 (5). Isomerization of 1 half arrow right over half arrow left 2 does not take place up to 80-degrees-C. X-Ray crystal structures are reported for trisilanes 3, IsMesSi(SiMe3)2 (4), and 5.

  DOI：

  10.1016/0022-328x(93)80035-a

文献信息

• Von Keyserlingk; Martens; Ostendorf, Journal of the Chemical Society. Perkin Transactions 1 (2001), 2001, # 8, p. 706 - 710
  作者：Von Keyserlingk、Martens、Ostendorf、Saak、Weidenbruch

  DOI：——

  日期：——
• Linear 2,2-diaryl-substituted trisilanes: Structure and photolysis to disilenes
  作者：R.Scott Archibald、Yvar van den Winkel、Douglas R. Powell、Robert West

  DOI：10.1016/0022-328x(93)80035-a

  日期：1993.3

  Synthesis of the new disilene, E/Z-IsMesSi=SiIsMes (1) is reported; the isomer Is2Si=SiMes2 (2) was obtained by photolysis of a mixture of Mes2Si(SiMe3)2 (3) and Is2Si(SiMe3)2 (5). Isomerization of 1 half arrow right over half arrow left 2 does not take place up to 80-degrees-C. X-Ray crystal structures are reported for trisilanes 3, IsMesSi(SiMe3)2 (4), and 5.