1,2R-diacetoxy-4R-hydroxy-n-heptadeca-16-ene | 1356361-35-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 1,2R-diacetoxy-4R-hydroxy-n-heptadeca-16-ene
• 英文别名: 1,2r-Diacetoxy-4r-hydroxy-n-heptadeca-16-ene；[(2R,4R)-2-acetyloxy-4-hydroxyheptadec-16-enyl] acetate
• CAS: 1356361-35-7
• 化学式: C₂₁H₃₈O₅
• 分子量: 370.53
• InChiKey: DKXUGBSIKPKTHC-NHCUHLMSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,2R-diacetoxy-4R-hydroxy-n-heptadeca-16-ene 在 sodium methylate 作用下， 以 乙腈 为溶剂， 生成 16-十七碳烯-1,2,4-三醇
  参考文献：
  名称：

  Heptadecanols from the leaves of Persea americana var. americana

  摘要：

  From the leaves of Persea americana var. americana, eleven heptadecanol derivatives were identified. Their structures were elucidated on the basis of spectroscopic analyses. The absolute configurations were determined by chemical reaction, NOESY experiment and further comparison of the optical rotation value with the literature value. Additionally, the ratios of the contents of six heptadecanol derivatives in leaves, immature fruits, mature fruits and seeds of P. americana were estimated by LC-MS in multiple reaction monitoring (MRM) mode. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.foodchem.2011.11.067

文献信息

• Heptadecanols from the leaves of Persea americana var. americana
  作者：Tzong-Huei Lee、Yow-Fu Tsai、Tzu-Tien Huang、Pi-Yu Chen、Wen-Li Liang、Ching-Kuo Lee

  DOI：10.1016/j.foodchem.2011.11.067

  日期：2012.5

  From the leaves of Persea americana var. americana, eleven heptadecanol derivatives were identified. Their structures were elucidated on the basis of spectroscopic analyses. The absolute configurations were determined by chemical reaction, NOESY experiment and further comparison of the optical rotation value with the literature value. Additionally, the ratios of the contents of six heptadecanol derivatives in leaves, immature fruits, mature fruits and seeds of P. americana were estimated by LC-MS in multiple reaction monitoring (MRM) mode. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.