| 115226-46-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 115226-46-5；55740-69-7
• 化学式: C₃₂H₃₀N₂O₄Pd₂
• 分子量: 719.441
• InChiKey: YNEZFYKKOJYMOP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 乙酰丙酮 以 二氯甲烷 为溶剂， 以92%的产率得到(C₆H₄CHNCH₂C₆H₅)Pd(CH₃COCHCOCH₃)
  参考文献：
  名称：

  C–N-palladacyclic-catalyzed Heck reaction in EGME/water: Rate and regioselectivity controlled by the solvents ratio

  摘要：

  Novel as well as known C, N-palladacyclic neutral complexes were tested as precatalyst in the Heck reaction between bromobenzene and styrene under aerobic conditions. The catalytic system Pd(II) complex/K2CO3/EGME-H2O (EGME = ethylene glycol monomethyl ether) showed to be highly efficient. Best performances of the catalysts were achieved by controlling the amount of water: generally a H2O content within the 25-50% v/v range resulted in the highest conversion of the substrates into trans-stilbene. As a matter of fact, bromobenzene and styrene can be converted quantitatively using only 0.01 mol% of precatalyst with very high regioselectivity for the trans product and with a TOF of 10000 h (1). In the absence of water, all complexes were less efficient and differences in their activity were found, while such a differentiation disappeared when water was added. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.03.017
• 作为产物：
  描述：

  palladium diacetate 、 溶剂黄146 、 苄胺 以 溶剂黄146 为溶剂， 以14%的产率得到
  参考文献：
  名称：

  再谈苄胺的环钯反应

  摘要：

  苄胺和乙酸钯（II）在甲苯或冰醋酸中以1：1的摩尔比在60°C下反应24小时，生成了乙酰胺桥联的苄胺（μ-OAc）2的环钯二聚体[Pd（ C 6 H 4 CH 2 NH 2）] 2（1）的产率分别为40–75％和20–40％。此外，化合物的混合物1，1D1式[（3-DC 6 ħ 3 CH 2 NH 2）的Pd]（μ-OAC）2 [的Pd（C 6 H ^ 4 CH 2 NH 2）]和1d2的式（μ-OAc）2 [Pd（3-DC 6 H 3 CH 2 NH 2）] 2通过一对一摩尔的苄胺和乙酸钯（II）进行单氘处理得到。乙酸（DOAc）在60°C下放置24小时。分离出这些混合物，产率为10％至30％，氘含量在0.7到0.9之间。此外，苄胺和钯（II）乙酸盐溶于下冰醋酸回流45分钟一对一的摩尔比处理产生的乙酸根桥接内切-cyclopalladated苄基苄基胺的二聚体（μ-OAC）2 [钯（C 6

  DOI：

  10.1016/s0277-5387(02)01338-4