2-(3-(3,5-bis(3,6-di(n-butyl)carbazol-9-yl)phenyl)phenyl-4-(3,5-bis(3,6-di(n-butyl)carbazol-9-yl)phenyl))pyridine | 1395102-55-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2-(3-(3,5-bis(3,6-di(n-butyl)carbazol-9-yl)phenyl)phenyl-4-(3,5-bis(3,6-di(n-butyl)carbazol-9-yl)phenyl))pyridine
• 英文别名: 9-[3-[2-[3-[3,5-Bis(3,6-dibutylcarbazol-9-yl)phenyl]phenyl]pyridin-4-yl]-5-(3,6-dibutylcarbazol-9-yl)phenyl]-3,6-dibutylcarbazole；9-[3-[2-[3-[3,5-bis(3,6-dibutylcarbazol-9-yl)phenyl]phenyl]pyridin-4-yl]-5-(3,6-dibutylcarbazol-9-yl)phenyl]-3,6-dibutylcarbazole
• CAS: 1395102-55-2
• 化学式: C₁₀₃H₁₀₉N₅
• 分子量: 1417.03
• InChiKey: YEXYHITZHXWSKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  33.1
• 重原子数：
  108
• 可旋转键数：
  31
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  32.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3,6-di-n-butylcarbazole 、 2-(3',5'-dichloro-[1,1'-biphenyl]-3-yl)-4-(3,5-dichlorophenyl)pyridine 在 三叔丁基膦 、 palladium diacetate 、 potassium carbonate 作用下， 以 邻二甲苯 为溶剂， 反应 24.0h， 以3.84 g的产率得到2-(3-(3,5-bis(3,6-di(n-butyl)carbazol-9-yl)phenyl)phenyl-4-(3,5-bis(3,6-di(n-butyl)carbazol-9-yl)phenyl))pyridine
  参考文献：
  名称：

  fac-Tris(2-phenylpyridine)iridium (III)s, covalently surrounded by six bulky host dendrons, for a highly efficient solution-processed organic light emitting device

  摘要：

  The fully surrounded complexes by six host dendrons showed high photoluminescence quantum efficiency in a neat film, comparable to in a dilute solution. The surrounding host dendrons efficiently suppressed intermolecular interaction between central Ir complexes and prevented concentration quenching. The complex, (mCP)(6)Ir, fully surrounded by six carbazole type hosts showed much better performance, compared with the complex, (DAP)(6)Ir, surrounded by arylamine type hosts, because of well balanced charge injection and transporting in the devices. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.orgel.2011.08.015

文献信息

• fac-Tris(2-phenylpyridine)iridium (III)s, covalently surrounded by six bulky host dendrons, for a highly efficient solution-processed organic light emitting device
  作者：Yong-Jin Pu、Noriaki Iguchi、Naoya Aizawa、Hisahiro Sasabe、Ken-ichi Nakayama、Junji Kido

  DOI：10.1016/j.orgel.2011.08.015

  日期：2011.12

  The fully surrounded complexes by six host dendrons showed high photoluminescence quantum efficiency in a neat film, comparable to in a dilute solution. The surrounding host dendrons efficiently suppressed intermolecular interaction between central Ir complexes and prevented concentration quenching. The complex, (mCP)(6)Ir, fully surrounded by six carbazole type hosts showed much better performance, compared with the complex, (DAP)(6)Ir, surrounded by arylamine type hosts, because of well balanced charge injection and transporting in the devices. (C) 2011 Elsevier B. V. All rights reserved.