F3T6-hP | 1190425-61-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: F3T6-hP
• 英文别名: 7-[7-[5-[5-[7-[5-[5-[7-[5-[5-(9,9-Dioctylfluoren-2-yl)thiophen-2-yl]thiophen-2-yl]-9,9-dioctylfluoren-2-yl]thiophen-2-yl]thiophen-2-yl]-9,9-dioctylfluoren-2-yl]thiophen-2-yl]thiophen-2-yl]-9,9-dioctylfluoren-2-yl]-18-hexyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone；7-[7-[5-[5-[7-[5-[5-[7-[5-[5-(9,9-dioctylfluoren-2-yl)thiophen-2-yl]thiophen-2-yl]-9,9-dioctylfluoren-2-yl]thiophen-2-yl]thiophen-2-yl]-9,9-dioctylfluoren-2-yl]thiophen-2-yl]thiophen-2-yl]-9,9-dioctylfluoren-2-yl]-18-hexyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 1190425-61-6
• 化学式: C₁₇₀H₁₉₄N₂O₄S₆
• 分子量: 2521.82
• InChiKey: QOIQJEBEKJALRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  59.7
• 重原子数：
  182
• 可旋转键数：
  71
• 环数：
  25.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  217
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  、 N-hexylperylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride 9,10-imide 在 四(三苯基膦)钯 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 24.0h， 以62%的产率得到F3T6-hP
  参考文献：
  名称：

  Monodisperse Co-oligomer Approach toward Nanostructured Films with Alternating Donor−Acceptor Lamellae

  摘要：

  A series of donor-acceptor (D-A) co-oligomers with oligo(fluorene-alt-bithiophene) and perylene diimide as donor and acceptor segments, respectively, have been designed and synthesized. They can self-assembly into alternating D-A lamellar nanostructured films with the periods depending on the molecular length. These films have been successfully used in fabrication of high-performance single-molecular solar cells with power conversion efficiency up to 1.50%.

  DOI：

  10.1021/ja905980w

文献信息

• Monodisperse Co-oligomer Approach toward Nanostructured Films with Alternating Donor−Acceptor Lamellae
  作者：Laju Bu、Xiaoyang Guo、Bo Yu、Yao Qu、Zhiyuan Xie、Donghang Yan、Yanhou Geng、Fosong Wang

  DOI：10.1021/ja905980w

  日期：2009.9.23

  A series of donor-acceptor (D-A) co-oligomers with oligo(fluorene-alt-bithiophene) and perylene diimide as donor and acceptor segments, respectively, have been designed and synthesized. They can self-assembly into alternating D-A lamellar nanostructured films with the periods depending on the molecular length. These films have been successfully used in fabrication of high-performance single-molecular solar cells with power conversion efficiency up to 1.50%.