2,3,6,7-tetrakis[3-diphenylphosphinopropylthio]tetrathiafulvalene | 1178859-24-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3,6,7-tetrakis[3-diphenylphosphinopropylthio]tetrathiafulvalene
• 英文别名: 3-[[2-[4,5-Bis(3-diphenylphosphanylpropylsulfanyl)-1,3-dithiol-2-ylidene]-5-(3-diphenylphosphanylpropylsulfanyl)-1,3-dithiol-4-yl]sulfanyl]propyl-diphenylphosphane；3-[[2-[4,5-bis(3-diphenylphosphanylpropylsulfanyl)-1,3-dithiol-2-ylidene]-5-(3-diphenylphosphanylpropylsulfanyl)-1,3-dithiol-4-yl]sulfanyl]propyl-diphenylphosphane
• CAS: 1178859-24-9
• 化学式: C₆₆H₆₄P₄S₈
• 分子量: 1237.66
• InChiKey: QBSBMOWHNJEZDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.1
• 重原子数：
  78
• 可旋转键数：
  28
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  202
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  cis-(tungsten tetracarbonyl bipiperidine) 、 2,3,6,7-tetrakis[3-diphenylphosphinopropylthio]tetrathiafulvalene 在 1,4-diazabicyclo[2.2.2]octane 作用下， 以 氯仿 、 甲苯 为溶剂， 以33%的产率得到[(W(CO)4)2(2,3,6,7-tetrakis(3-diphenylphosphinobutylthio)tetrathiafulvalene)]
  参考文献：
  名称：

  Bimetallamacrocycles involving tetrakis(diphenylphosphinoalkylthio)tetrathiafulvalene

  摘要：

  Two novel tetrathiafulvalene (TTF) ligands, substituted by four diphenylphosphinoalkylthio groups, have been synthesized and characterized. Their redox properties, determined by cyclic voltammetry, have been compared with their precursors and discussed. The ability of these redox active ligands to react with two equivalent of cis-W(CO)(4)(C5H11N)(2) is presented. X-ray crystal structure of a bis 13-metallamacrocycle is reported together with its redox behaviour. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.006
• 作为产物：
  描述：

  2,3,6,7-tetrakis[4-(boronatodiphenylphosphino)propylthio]tetrathiafulvalene 在 三乙烯二胺 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以71%的产率得到2,3,6,7-tetrakis[3-diphenylphosphinopropylthio]tetrathiafulvalene
  参考文献：
  名称：

  Bimetallamacrocycles involving tetrakis(diphenylphosphinoalkylthio)tetrathiafulvalene

  摘要：

  Two novel tetrathiafulvalene (TTF) ligands, substituted by four diphenylphosphinoalkylthio groups, have been synthesized and characterized. Their redox properties, determined by cyclic voltammetry, have been compared with their precursors and discussed. The ability of these redox active ligands to react with two equivalent of cis-W(CO)(4)(C5H11N)(2) is presented. X-ray crystal structure of a bis 13-metallamacrocycle is reported together with its redox behaviour. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.006

文献信息

• Bimetallamacrocycles involving tetrakis(diphenylphosphinoalkylthio)tetrathiafulvalene
  作者：Grégory Gachot、Pascal Pellon、Thierry Roisnel、Dominique Lorcy

  DOI：10.1016/j.jorganchem.2009.04.006

  日期：2009.7

  Two novel tetrathiafulvalene (TTF) ligands, substituted by four diphenylphosphinoalkylthio groups, have been synthesized and characterized. Their redox properties, determined by cyclic voltammetry, have been compared with their precursors and discussed. The ability of these redox active ligands to react with two equivalent of cis-W(CO)(4)(C5H11N)(2) is presented. X-ray crystal structure of a bis 13-metallamacrocycle is reported together with its redox behaviour. (C) 2009 Elsevier B.V. All rights reserved.