9-Butyl-3,6-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]carbazole | 1006046-80-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-Butyl-3,6-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]carbazole
• 英文别名: 9-butyl-3,6-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]carbazole
• CAS: 1006046-80-5
• 化学式: C₇₆H₁₀₅NO₄
• 分子量: 1096.67
• InChiKey: ZDSUMWSBOAHEPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.9
• 重原子数：
  81
• 可旋转键数：
  49
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  41.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-iodo-2,5-bis(trimethylsilylacetylene)benzene 、 9-Butyl-3,6-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]carbazole 在 bis-triphenylphosphine-palladium(II) chloride copper(l) iodide 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以58%的产率得到2-[2-[2-[4-[2-[6-[2-[4-[2-[2,5-Bis(2-trimethylsilylethynyl)phenyl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-9-butylcarbazol-3-yl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-4-(2-trimethylsilylethynyl)phenyl]ethynyl-trimethylsilane
  参考文献：
  名称：

  Synthesis of a Nanocar with an Angled Chassis. Toward Circling Movement

  摘要：

  Nanocars with an angled chassis have been synthesized and imaged using scanning tunneling microscopy. These angled chassis nanocars were designed to further our understanding of the directional control and surface-rolling capabilities of this class of nanomachines. The alkylated carbazole inner core might enable the molecular scaffold to produce circular rolling motions of the nanovehicles on surfaces.

  DOI：

  10.1021/ol702642r
• 作为产物：
  描述：

  2-[4-[2-[9-Butyl-6-[2-[2,5-didecoxy-4-(2-trimethylsilylethynyl)phenyl]ethynyl]carbazol-3-yl]ethynyl]-2,5-didecoxyphenyl]ethynyl-trimethylsilane 在 甲醇 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以96%的产率得到9-Butyl-3,6-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]carbazole
  参考文献：
  名称：

  Synthesis of a Nanocar with an Angled Chassis. Toward Circling Movement

  摘要：

  Nanocars with an angled chassis have been synthesized and imaged using scanning tunneling microscopy. These angled chassis nanocars were designed to further our understanding of the directional control and surface-rolling capabilities of this class of nanomachines. The alkylated carbazole inner core might enable the molecular scaffold to produce circular rolling motions of the nanovehicles on surfaces.

  DOI：

  10.1021/ol702642r

文献信息

• Synthesis of a Nanocar with an Angled Chassis. Toward Circling Movement
  作者：Takashi Sasaki、Andrew J. Osgood、Lawrence B. Alemany、Kevin F. Kelly、James M. Tour

  DOI：10.1021/ol702642r

  日期：2008.1.1

  Nanocars with an angled chassis have been synthesized and imaged using scanning tunneling microscopy. These angled chassis nanocars were designed to further our understanding of the directional control and surface-rolling capabilities of this class of nanomachines. The alkylated carbazole inner core might enable the molecular scaffold to produce circular rolling motions of the nanovehicles on surfaces.