N-hexyl-1,8-dimethylazaperylene-8,9-dicarboximide | 1226763-72-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N-hexyl-1,8-dimethylazaperylene-8,9-dicarboximide
• 英文别名: 16-Hexyl-5,7-dimethyl-4,16-diazahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(20),2,4,6,8,10(23),11(21),12,14(22),18-decaene-15,17-dione；16-hexyl-5,7-dimethyl-4,16-diazahexacyclo[12.6.2.12,6.011,21.018,22.010,23]tricosa-1(20),2,4,6,8,10(23),11(21),12,14(22),18-decaene-15,17-dione
• CAS: 1226763-72-9
• 化学式: C₂₉H₂₆N₂O₂
• 分子量: 434.538
• InChiKey: YWYFCFKJNFSLQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  33
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  50.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  5-(1,8-N-hexyldicarboximidenaphthyl)-1,8-dimethylisoquinoline 在 1,5-二氮杂双环[4.3.0]壬-5-烯 、 potassium tert-butylate 作用下， 以12%的产率得到N-hexyl-1,8-dimethylazaperylene-8,9-dicarboximide
  参考文献：
  名称：

  Synthesis and Properties of Dicarboximide Derivatives of Perylene and Azaperylene

  摘要：

  The N-alkyl dicarboximide derivatives of naphthylisoquinoline and binaphthalene were prepared by the hetero coupling reaction of the corresponding N-alkyl dicarboximide derivatives of stannylnaphthalene with bromodimethyisoquinoline and bromodimethylnaphthalene, respectively. The ring closing of the N-hexyl derivatives of naphthylisoquinoline and binaphthalene produced the N-hexyldicarboximide derivatives of azaperylene and perylene having the same substituents, respectively. The absorption spectra and fluorescence spectra of the azaperylene and perylene derivatives were investigated.

  DOI：

  10.3987/com-09-s(s)104

文献信息

• Synthesis and Properties of Dicarboximide Derivatives of Perylene and Azaperylene
  作者：Yukinori Nagao、Tatsurou Yoshida、Koji Arimitsu、Kozo Kozawa

  DOI：10.3987/com-09-s(s)104

  日期：——

  The N-alkyl dicarboximide derivatives of naphthylisoquinoline and binaphthalene were prepared by the hetero coupling reaction of the corresponding N-alkyl dicarboximide derivatives of stannylnaphthalene with bromodimethyisoquinoline and bromodimethylnaphthalene, respectively. The ring closing of the N-hexyl derivatives of naphthylisoquinoline and binaphthalene produced the N-hexyldicarboximide derivatives of azaperylene and perylene having the same substituents, respectively. The absorption spectra and fluorescence spectra of the azaperylene and perylene derivatives were investigated.