(9Z,10E)-N9,N10-bis(2,6-dichlorophenyl)phenanthrene-9,10-diimine | 1354657-05-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: (9Z,10E)-N9,N10-bis(2,6-dichlorophenyl)phenanthrene-9,10-diimine
• CAS: 1354657-05-8
• 化学式: C₂₆H₁₄Cl₄N₂
• 分子量: 496.223
• InChiKey: OWCYVCIGRJBNKC-FNKNYVMZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.22
• 重原子数：
  32.0
• 可旋转键数：
  2.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  菲醌 、 2,6-二氯苯胺 在 四氯化钛 作用下， 以 甲苯 为溶剂， 生成 、 (9Z,10E)-N9,N10-bis(2,6-dichlorophenyl)phenanthrene-9,10-diimine
  参考文献：
  名称：

  N,N′-Disubstituted phenanthrene-9,10-diimines: synthesis and NMR spectroscopic study

  摘要：

  Novel aryl-aryl, alkyl-alkyl, aryl-alkyl N,N'-disubstituted phenanthrene-9,10-diimines were synthesized by condensation of 9,10-phenanthrenequinone with primary amines. The novel two-stage method of synthesis of disubstituted phenanthrene-9,10-diimines with identical or different aryl and alkyl sub-stituents at the nitrogen atom was established. The investigated compounds undergo slow Z-EIE-Z interconversion which was studied by NMR spectroscopy. Thermodynamic parameters of interconversion were obtained by variable temperature NMR spectroscopy. (C) 2011 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tet.2011.12.028