[5,15-Bis(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc | 1093122-85-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [5,15-Bis(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc
• CAS: 1093122-85-0
• 化学式: C₆₈H₉₀B₂N₄O₈Zn
• 分子量: 1178.5
• InChiKey: FYHBDGJLXQNWMD-XMLBZSBISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [5-(4-bromophenyl)-10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc 、 [5,15-Bis(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc 在 四(三苯基膦)钯 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 24.0h， 以26%的产率得到Zn3(((HexO)2C6H3)2C20H9N4C6H4C20H8N4(C6H3(OHex)2)2C6H4C20H9N4(C6H3(OHex)2)2)
  参考文献：
  名称：

  Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation

  摘要：

  Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by sotution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

  DOI：

  10.1021/ja804014y
• 作为产物：
  描述：

  [5,15-dibromo-10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc 、 频那醇硼烷 在 bis-triphenylphosphine-palladium(II) chloride 、 三乙胺 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 12.0h， 以82%的产率得到[5,15-Bis(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)-10,20-bis[2,6-bis(n-hexoxy)phenyl]porphinato]zinc
  参考文献：
  名称：

  Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation

  摘要：

  Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by sotution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

  DOI：

  10.1021/ja804014y