| 1382787-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 1382787-01-0
• 化学式: C₉₀H₁₁₀N₂O₉
• 分子量: 1363.87
• InChiKey: WSQNFHCZNOZUSK-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 苯甲腈 、 三乙胺 作用下， 生成
  参考文献：
  名称：

  Selective photoinduced single or double electron reduction of perylenebisimides

  摘要：

  Selective single and double electron reduction of two soluble perylenebisimides was performed by irradiating these compounds in benzonitrile solutions containing triethylamine 10(-2) M. Lamp irradiation in the absence of oxygen generates, consecutively, the corresponding radical anion and dianion as persistent species, depending of the irradiation time. These negative PBI species were persistent long enough to be characterized by optical and EPR spectroscopies. Laser flash photolysis determines that the kinetics of PBI reduction follows two first order processes assigned to the presence of two different populations of solvated electrons in the medium. The fastest reduction takes place in tens of microseconds and the slowest occurs with a lifetime longer than hundred microseconds. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2012.01.008
• 作为产物：
  描述：

  在 氧气 作用下， 以 苯甲腈 为溶剂， 生成
  参考文献：
  名称：

  Selective photoinduced single or double electron reduction of perylenebisimides

  摘要：

  Selective single and double electron reduction of two soluble perylenebisimides was performed by irradiating these compounds in benzonitrile solutions containing triethylamine 10(-2) M. Lamp irradiation in the absence of oxygen generates, consecutively, the corresponding radical anion and dianion as persistent species, depending of the irradiation time. These negative PBI species were persistent long enough to be characterized by optical and EPR spectroscopies. Laser flash photolysis determines that the kinetics of PBI reduction follows two first order processes assigned to the presence of two different populations of solvated electrons in the medium. The fastest reduction takes place in tens of microseconds and the slowest occurs with a lifetime longer than hundred microseconds. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2012.01.008