Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+) | 184765-68-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)
• CAS: 184765-68-2
• 化学式: C₆₅H₆₁Cl₇MnN₄O₇
• 分子量: 1313.33
• InChiKey: DYRNCRKFTDPXRY-PFPHGEOVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin 、 manganese (II) acetate tetrahydrate 以 N,N-二甲基甲酰胺 为溶剂， 以100%的产率得到Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)
  参考文献：
  名称：

  Mn(III)-tetraarylporphyrins bearing covalently bonded crown-ethers: synthesis and catalytic activity in 1-dodecene epoxidation promoted by aqueous HOClOCl−

  摘要：

  Mn(III)-complexes of tetraarylporphyrins 1-4 bearing a crown-ether covalently linked through a single flexible chain have been synthesized. Their basic frame is that of the robust tetra-(2,6-dichlorophenyl)porphyrin 5 and the chain is connected by ether linkage either to the ortho (1-2) or to the meta positions (3-4) of one meso-aryl group. Catalytic efficiency was tested in the epoxidation of the poorly reactive 1-dodecene at 0 degrees C under CH2Cl2/H2O two-phase conditions in the presence of NaOCl (pH 9.5-10.0) as oxygen donor. The results obtained led us to propose a general acid/base catalysis as an explanation for the positive effect of crown-ethers in the alkene epoxidations with this catalytic system.

  DOI：

  10.1016/s1381-1169(96)00154-9