poly[[bis(pyridin-3-ol)manganese(II)]-di-μ-pyridin-3-olato] | 853072-42-1

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: poly[[bis(pyridin-3-ol)manganese(II)]-di-μ-pyridin-3-olato]
• CAS: 853072-42-1
• 化学式: C₂₀H₁₈MnN₄O₄
• 分子量: 433.325
• InChiKey: FMKBOIANPODEMW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-羟基吡啶 、 manganese (II) acetate tetrahydrate 以 水 为溶剂， 生成 poly[[bis(pyridin-3-ol)manganese(II)]-di-μ-pyridin-3-olato]
  参考文献：
  名称：

  Poly[[bis(pyridin-3-ol)manganese(II)]-di-μ-pyridin-3-olato]

  摘要：

  In the title complex, [Mn(C5H4NO)(2)(C5H5NO)(2)](n) or [Mn(mu-3-PyO)(2)(3-PyOH)(2)](n) (3-PyO- is the pyridin-3-olate anion and 3-PyOH is pyridin-3-ol), the Mu(II) atom lies on an inversion centre and has octahedral geometry, defined by two N atoms and two deprotonated exocyclic O atoms of symmetry-related pyridin-3-olate ligands [Mn-N = 2.3559 (14) Angstrom and Mn- O = 2.1703 (11) Angstrom], as well as two N atoms of terminal 3-PyOH ligands [Mn-N = 2.3482 (13) Angstrom]. The Mu(II) atoms are bridged by the deprotonated pyridin-3-olate anion into a layer structure, generating sheets in the (101) plane. These sheets are linked by O-H...O hydrogen bonds. There are also pi-pi and C-H...pi interactions in the crystal structure.

  DOI：

  10.1107/s0108270105001101