Acetic acid (4aR,6S,7R,8S,8aS)-6-benzyloxy-8-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester | 233767-43-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡喃二恶英
• 英文名称: Acetic acid (4aR,6S,7R,8S,8aS)-6-benzyloxy-8-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
• CAS: 233767-43-6
• 化学式: C₂₂H₂₄O₇
• 分子量: 400.428
• InChiKey: FABKDNZDZKMZMQ-DNJZHPGESA-N

反应信息

• 作为反应物：
  描述：

  Acetic acid (4aR,6S,7R,8S,8aS)-6-benzyloxy-8-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 在 palladium on activated charcoal 氢气 、 三氟乙酸 作用下， 反应 2.0h， 生成 α-D-2-O-acetyl-glucopyranose
  参考文献：
  名称：

  On the analogy between forskolin and D-glucose

  摘要：

  2-O-Acetyl-D-glucose was synthesized in order to evaluate the influence of an acyl group on the binding with the glucose carrier protein (GluT); as its affinity neighbours that of glucose itself, the glucose forskolin analogy appears to be coincidental and several explanations are proposed. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(99)00270-x
• 作为产物：
  描述：

  乙酰氯 、 benzyl 4,6-O-benzylidene-α-D-glucopyranoside 在 二正丁基氧化锡 、 三乙胺 作用下， 生成 Acetic acid (4aR,6S,7R,8S,8aS)-6-benzyloxy-8-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester
  参考文献：
  名称：

  On the analogy between forskolin and D-glucose

  摘要：

  2-O-Acetyl-D-glucose was synthesized in order to evaluate the influence of an acyl group on the binding with the glucose carrier protein (GluT); as its affinity neighbours that of glucose itself, the glucose forskolin analogy appears to be coincidental and several explanations are proposed. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0960-894x(99)00270-x