[(tetra(p-tolyl)porphyrinato)Zn(NC5H3(NCHC6H2(C(CH3)3)2O)2)Ni] | 1143464-63-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [(tetra(p-tolyl)porphyrinato)Zn(NC5H3(NCHC6H2(C(CH3)3)2O)2)Ni]
• CAS: 1143464-63-4
• 化学式: C₈₃H₈₁N₇NiO₂Zn
• 分子量: 1332.68
• InChiKey: CSTOPQCTYAOSLB-FTSWCUASSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5,10,15,20-tetrakis(4-methylphenyl)porphyrin 、 (C5H3N(NCHC6H2(O)(tBu)2)2)Zn 、 nickel(II) acetate tetrahydrate 以 四氢呋喃 为溶剂， 以99%的产率得到[(tetra(p-tolyl)porphyrinato)Zn(NC5H3(NCHC6H2(C(CH3)3)2O)2)Ni]
  参考文献：
  名称：

  Access to hybrid supramolecular salen–porphyrin assemblies via a selective in situ transmetalation–metalation self-assembly sequence

  摘要：

  New supramolecular hybrid assemblies have been selectively prepared starting off with stoichiometric mixtures of pyridine-tagged Zn(salphen) and non-metalated porphyrin ligands in the presence of suitable metal acetates. This one-pot procedure leads to in situ transmetalation of the salen unit, metalation of the porphyrin ligand by the released Zn(OAc)(2) and subsequent heterometallic assembly formation between the metallosalen and metalloporphyrin components via Zn-N-pyr coordination motifs. The reactions were followed by NMR spectroscopy and MALDI-TOF mass spectrometry, and for one of the Zn(salphen) building blocks the X-ray molecular structure is reported. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.05.022