Spiro<(3,3-diphenyl-1,2,4-trioxolane)-5,9'-(10'-oxo-9',10'-dihydrophenanthrene)> | 136460-10-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Spiro<(3,3-diphenyl-1,2,4-trioxolane)-5,9'-(10'-oxo-9',10'-dihydrophenanthrene)>
• 英文别名: Spiro[(3,3-diphenyl-1,2,4-trioxolane)-5,9'-(10'-oxo-9',10'-dihydrophenanthrene)]；5,5-Diphenylspiro[1,2,4-trioxolane-3,10'-phenanthrene]-9'-one
• CAS: 136460-10-1
• 化学式: C₂₇H₁₈O₄
• 分子量: 406.438
• InChiKey: QXFHZXDKMABUDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (2-methoxyethene-1,1-diyl)dibenzene 、 菲醌 在 臭氧 作用下， 以 二氯甲烷 为溶剂， 以74%的产率得到Spiro<(3,3-diphenyl-1,2,4-trioxolane)-5,9'-(10'-oxo-9',10'-dihydrophenanthrene)>
  参考文献：
  名称：

  Ozonolysis of vinyl ethers in the presence of .alpha.-diketones and .alpha.-keto esters

  摘要：

  Ozonolysis of vinyl ethers in the presence of alpha-diketones provided two types of products, i.e., a Baeyer-Villiger oxidation product and 3-acyl-1,2,4-trioxolane. The evidence suggests that the latter product is labile and, therefore, the former one might be produced by decomposition of the latter. In contrast, 1,2,4-trioxolane-3-carboxylates were stable. As a result, ozonolysis of vinyl ethers in the presence of alpha-keto esters yielded the expected ozonides in high yield.

  DOI：

  10.1021/jo00023a026