Co3(μ-dmpz)4(Hdmpz)2(OOCMe)2 | 1189793-84-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: Co3(μ-dmpz)4(Hdmpz)2(OOCMe)2
• 英文别名: Co3(μ-3,5-dimethylpyrazole(-1H))4(3,5-dimethylpyrazole)2(acetate)2
• CAS: 1189793-84-7
• 化学式: C₃₄H₅₀Co₃N₁₂O₄
• 分子量: 867.829
• InChiKey: XKYZIVMSGDQMGH-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 cobalt(II) diacetate tetrahydrate 以 xylene 为溶剂， 以90%的产率得到Co3(μ-dmpz)4(Hdmpz)2(OOCMe)2
  参考文献：
  名称：

  Synthesis and structure of trinuclear pyrazolate-bridged acetates M3(μ-dmpz)4(Hdmpz)2(OOCMe)2 (M = Zn or Co; Hdmpz = 3,5-dimethylpyrazole)

  摘要：

  We discovered that reactions of hydrous cobalt and zinc acetates with 3,5-dimethylpyrazole (Hdmpz) in boiling xylene or toluene or upon the thermolysis of solid precursors (150A degrees C) yield trinuclear pyrazolate-bridged complexes M-3 (mu-dmpz)(4)(Hdmpz)(2) (OOCMe)(2)(M = Zn or Co). Depending on the crystallization conditions, these complexes contain various solvating molecules (benzene, toluene, or Hdmpz), which influences the character of intramolecular and intermolecular hydrogen bonding, as shown by X-ray crystallography.

  DOI：

  10.1134/s0036023609110060