manganese(II) bis(2,5-diamino-1,3,4-thiadiazole)diaqua dichloride | 148387-38-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: manganese(II) bis(2,5-diamino-1,3,4-thiadiazole)diaqua dichloride
• CAS: 148387-38-6
• 化学式: C₄H₁₂Cl₂MnN₈O₂S₂
• 分子量: 394.168
• InChiKey: NMQZHGXCDNMGIF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 2,5-二氨基-1,3,4-噻二唑 以 水 为溶剂， 生成 manganese(II) bis(2,5-diamino-1,3,4-thiadiazole)diaqua dichloride
  参考文献：
  名称：

  Synthesis, crystal and molecular structure, and spectroscopic properties of manganese(II) bis(2,5-diamino-1,3,4-thiadiazole) diaqua dichloride

  摘要：

  The reaction product of manganese(II) chloride and 2,5-diamino-1,3,4-thiadiazole was prepared and characterized by means of structural, and spectroscopic measurements. The crystals are monoclinic, space group C2/c, with a = 12.403(4), b = 10.742(2), c = 10.449(5)angstrom, beta = 92.61(3)degrees, and Z = 4. The structure was solved by the heavy-atom method, and least-squares refinement of structural parameters led to a conventional R factor of 0.020 for 1518 independent reflections. The structure consists of discrete molecules with twofold symmetry in which the manganese atom is coordinated in slightly distorted octahedral geometry by two nitrogen, two oxygen and two chlorine atoms.

  DOI：

  10.1007/bf01263593