CuBr(4-bromo-2-[(pyridin-2-ylmethylimino)methyl]phenol) | 1403619-90-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: CuBr(4-bromo-2-[(pyridin-2-ylmethylimino)methyl]phenol)
• CAS: 1403619-90-8
• 化学式: C₁₃H₁₀Br₂CuN₂O
• 分子量: 433.589
• InChiKey: CGYPBIPQECSZMW-OLIKVXRNSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 4-bromo-2-[(pyridin-2-ylmethylimino)methyl]phenol 、 copper(ll) bromide 以 甲醇 为溶剂， 反应 1.0h， 以19%的产率得到CuBr(4-bromo-2-[(pyridin-2-ylmethylimino)methyl]phenol)
  参考文献：
  名称：

  Synthesis and Crystal Structures of Schiff Base Copper(II) Complexes [CuBrL] and [CuL(NCS)]

  摘要：

  CuBr2 reacts with the Schiff base 4-bromo-2-[(pyridin-2-ylmethylimino)methyl]phenol (HL) and ammonium thiocyanate in absolute methanol to give the mononuclear copper(II) complexes [CuBrL] (1) and [CuL(NCS)] (2). Both complexes were characterized by elemental analysis, IR spectra, and single-crystal X-ray determination. The crystal of (1) crystallizes in the monoclinic space group P2(1)/c, with a = 7.754(2), b = 10.542(3), c = 17.674(2) angstrom, beta = 114.445(2)degrees, V = 1315.2(5) angstrom(3), Z = 4. The crystal of (2) crystallizes in the monoclinic space group P2(1)/n, with a = 7.016(1), b = 15.559(2), c = 13.197(1) angstrom, beta = 91.647(2)degrees, V = 1440.0(4) angstrom(3), Z = 4. The Cu atom in each of the complexes is in a square planar geometry.

  DOI：

  10.1080/15533174.2012.680169