| 21246-10-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 21246-10-6
• 化学式: C₅H₈N₂O₃*Cu*H₂O
• 分子量: 225.691
• InChiKey: XROSSHODWTZMFM-HWYNEVGZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.98
• 重原子数：
  12.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  133.07
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  咪唑 、 以 水 为溶剂， 生成
  参考文献：
  名称：

  Paramagnetic resonance and visible spectroscopic properties of binuclear Cu–Cu and Cu–Zn imidazolate-bridged complexes: effective model for active site of superoxide dismutase

  摘要：

  Syntheses of the imidazolate-bridged heterometallic binuclear copper-zinc complex [(glyala)Cu-im-Zn(glyala)]Na, where H(2)glyala = glycylalanine, and im = imidazolate ion, has been achieved. X-band e.p.r and Visible absorption spectra of the complex [(glyala)Cu-im-Zn(glyala)]Na at different pH values in frozen solution (50% aqueous DMSO, 77K) show that the imidazolate-bridged complex is stable in the pH range 7.15-10.50. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(00)00341-3
• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 甘氨酰丙氨酸 以 水 为溶剂， 生成
  参考文献：
  名称：

  Paramagnetic resonance and visible spectroscopic properties of binuclear Cu–Cu and Cu–Zn imidazolate-bridged complexes: effective model for active site of superoxide dismutase

  摘要：

  Syntheses of the imidazolate-bridged heterometallic binuclear copper-zinc complex [(glyala)Cu-im-Zn(glyala)]Na, where H(2)glyala = glycylalanine, and im = imidazolate ion, has been achieved. X-band e.p.r and Visible absorption spectra of the complex [(glyala)Cu-im-Zn(glyala)]Na at different pH values in frozen solution (50% aqueous DMSO, 77K) show that the imidazolate-bridged complex is stable in the pH range 7.15-10.50. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(00)00341-3