bis(acetylacetonato)[3,6-bis(4'-(butyloxy)phenyl)pyridazine]dipalladium | 373387-86-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: bis(acetylacetonato)[3,6-bis(4'-(butyloxy)phenyl)pyridazine]dipalladium
• CAS: 373387-86-1
• 化学式: C₃₄H₄₀N₂O₆Pd₂
• 分子量: 785.541
• InChiKey: FHTYKLJCUSLHIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(μ-acetato)[3,6-bis(4'-(butyloxy)phenyl)pyridazine]dipalladium 、 sodium (Z)-4-oxopent-2-en-2-olate 以 四氢呋喃 为溶剂， 以84%的产率得到bis(acetylacetonato)[3,6-bis(4'-(butyloxy)phenyl)pyridazine]dipalladium
  参考文献：
  名称：

  Doubly Cyclometalated Pyridazines:  Contrasting Behavior with Palladium and Platinum

  摘要：

  The cyclometalation of 3,6-diphenylpyridazines with palladium and platinum has been studied. When palladium acetate is used as the metal source, two sequential cyclometalations are observed, with the first cyclometalation deactivating the system toward a second cyclometalation. Both monocyclopalladated and dicyclopalladated species have been isolated and characterized as their acetylacetonate derivatives. When potassium tetrachloroplatinate is used as the metal source, only double cycloplatination is observed: the first cycloplatination activates the system toward a second cycloplatination through a combination of nitrogen coordination and a chloride bridging two platinums. A doubly cycloplatinated compound has been isolated as its triphenylphosphine derivative, which has been fully characterized: the single-crystal X-ray structure shows that the two platinums are bridged by a chloride.

  DOI：

  10.1021/om010449g