3-chlorocyclo[7.1.0.0^2,4]dec-2-ene | 245517-52-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 3-chlorocyclo[7.1.0.0^2,4]dec-2-ene
• 英文别名: 3-Chlorotricyclo[7,1,0,0 2,4]dec-2-ene；10-chlorotricyclo[7.1.0.02,4]dec-1(10)-ene
• CAS: 245517-52-6
• 化学式: C₁₀H₁₃Cl
• 分子量: 168.666
• InChiKey: YQEDECMDPKEXTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-chlorocyclo[7.1.0.0^2,4]dec-2-ene 反应 1.0h， 生成 3-chlorobicyclo[7.1.0]deca-1,4-diene
  参考文献：
  名称：

  Dehydrohalogenation of adducts of dichlorocarbene with cyclooctene and its peripherally cyclopropanated analogs

  摘要：

  Dehydrohalogenation of three isomeric adducts of dichlorocarbene with bicyclo[6.1.0]non-1-, -2-, and -4-enes under the action of potassium tert-butoxide in DMSO was studied. In the course of dehydrohalogenation of the substrates under study, different isomerization processes, which were accompanied by repeated migrations of multiple bonds that formed, occurred depending on the structure of dichlorides, while no skeletal rearrangements were observed.

  DOI：

  10.1007/bf02494639
• 作为产物：
  描述：

  环辛二烯 在 sodium hydroxide 、 potassium tert-butylate 、 苄基三乙基氯化铵 、 lithium 作用下， 以 正己烷 、 二甲基亚砜 、 叔丁醇 为溶剂， 反应 5.0h， 生成 3-chlorocyclo[7.1.0.0^2,4]dec-2-ene
  参考文献：
  名称：

  Dehydrohalogenation of adducts of dichlorocarbene with cyclooctene and its peripherally cyclopropanated analogs

  摘要：

  Dehydrohalogenation of three isomeric adducts of dichlorocarbene with bicyclo[6.1.0]non-1-, -2-, and -4-enes under the action of potassium tert-butoxide in DMSO was studied. In the course of dehydrohalogenation of the substrates under study, different isomerization processes, which were accompanied by repeated migrations of multiple bonds that formed, occurred depending on the structure of dichlorides, while no skeletal rearrangements were observed.

  DOI：

  10.1007/bf02494639