1,2-epoxy-6-(9-carbazolyl)-4-oxahexane | 82684-69-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1,2-epoxy-6-(9-carbazolyl)-4-oxahexane
• 英文别名: 9-[2-(oxiran-2-ylmethoxy)ethyl]-9H-carbazole；2-(carbazol-9-yl)ethanol glycidyl ether；9H-Carbazole, 9-[2-(oxiranylmethoxy)ethyl]-；9-[2-(oxiran-2-ylmethoxy)ethyl]carbazole
• CAS: 82684-69-3
• 化学式: C₁₇H₁₇NO₂
• 分子量: 267.327
• InChiKey: POHKSKVXKVFBTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  26.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  咔唑 、 1,2-epoxy-6-(9-carbazolyl)-4-oxahexane 在 potassium hydroxide 作用下， 以 丁酮 为溶剂， 以68%的产率得到1,6-di(carbazol-9-yl)-4-oxa-2-hexanol
  参考文献：
  名称：

  Photoinduced Optical Functionalism of Branched Azophenylcarbazoles in Molecular Glass Matrices

  摘要：

  A new guest-host composition of 3-(4-nitrophenyl) azo-9-(2-ethyl) hexyl-2-(2-ethyl) hexyloxycarbazole as chromophore and 2,2-bis{4-[2-hydroxy-9-(carbazol-9-yl)-5-(carbazol-9-methyl)-4,7-dioxanonyloxy] phenyl} propane (molecular glass) as host for all-optical poling application was developed and investigated. A comparison between molecular glass and commonly used bisphenol Z polycarbonate as host showed a slightly better ability for the molecular glass to keep the azophenylcarbazole molecules oriented. Erasure while reading the non-centrosymmetry created is demonstrated and explained. Using an adopted model orientational diffusion coefficient, lifetime of cis isomer and probabilities of redistribution were evaluated.

  DOI：

  10.1080/15421406.2012.635936
• 作为产物：
  描述：

  9-咔唑乙醇 、 环氧氯丙烷 在 potassium carbonate 、 potassium hydroxide 作用下， 反应 3.0h， 以85.2%的产率得到1,2-epoxy-6-(9-carbazolyl)-4-oxahexane
  参考文献：
  名称：

  三苯基碳鎓盐作为热潜伏和光潜伏引发剂的含咔唑基环氧单体的阳离子开环聚合

  摘要：

  摘要带有咔唑部分，9- [3-（烯丙氧基）-2-（环氧乙烷-2-基甲氧基）丙基] -9 H-咔唑，9- [3-甲氧基-2-（环氧乙烷-）的各种环氧单体的光引发阳离子聚合2-基甲氧基）丙基] -9 H-咔唑，9- [2-（环氧乙烷-2-基甲氧基）乙基] -9 H-咔唑以及3,6-二溴-9-（环氧乙烷-2）的组成基甲基）-9 ħ与3,4-环氧环己基-3,4-环氧环己烷羧酸酯-咔唑进行批量使用具有阴离子如BF三苯基碳盐调查4 - ，的SnCl 5 - ，和的SbCl 6 -。研究了在引发剂存在下咔唑基单体的黑暗聚合。这些光诱导的聚合反应给出聚合度为4-22的低聚物。讨论了光引发剂阴离子和聚合时间对聚合反应的影响。 图形概要

  DOI：

  10.1007/s00706-008-0090-6

文献信息

• Photoinduced Optical Functionalism of Branched Azophenylcarbazoles in Molecular Glass Matrices
  作者：G. Seniutinas、T. Malinauskas、R. Tomašiūnas、R. Petruškevičius、I. Petrikytė、V. Getautis

  DOI：10.1080/15421406.2012.635936

  日期：2012.5.3

  A new guest-host composition of 3-(4-nitrophenyl) azo-9-(2-ethyl) hexyl-2-(2-ethyl) hexyloxycarbazole as chromophore and 2,2-bis4-[2-hydroxy-9-(carbazol-9-yl)-5-(carbazol-9-methyl)-4,7-dioxanonyloxy] phenyl} propane (molecular glass) as host for all-optical poling application was developed and investigated. A comparison between molecular glass and commonly used bisphenol Z polycarbonate as host showed a slightly better ability for the molecular glass to keep the azophenylcarbazole molecules oriented. Erasure while reading the non-centrosymmetry created is demonstrated and explained. Using an adopted model orientational diffusion coefficient, lifetime of cis isomer and probabilities of redistribution were evaluated.
• ZHEREBTSOV I. P.; LIPINA Z. I., KEMEROV. NII XIM. PROM-STI. KEMEROVO, 1980. 8 S., BIBLIOGR. 12 NAZV. (RUK+
  作者：ZHEREBTSOV I. P.、 LIPINA Z. I.

  DOI：——

  日期：——
• STANISHAUSKAJTE, A. A.;LEJTAJTE, A. I., LITNIINTI 1403LI-85
  作者：STANISHAUSKAJTE, A. A.、LEJTAJTE, A. I.

  DOI：——

  日期：——
• [EN] OPTICAL SENSOR WITH ELECTROLUMINESCENT LIGHT SOURCE AND POLYMER LIGHT DETECTOR<br/>[FR] DETECTEUR OPTIQUE A SOURCE DE LUMIERE ELECTROLUMINESCENTE ET A DETECTEUR DE LUMIERE POLYMERE
  申请人：FCI-FIBERCHEM, INC.

  公开号：WO1994017556A1

  公开（公告）日：1994-08-04

  (EN) An optical sensor (10) is produced with a polymer based light source (18) and/or polymer based light detector (28). An electroluminescent source (18) has a conducting polymer layer (20) or alternatively a phosphor layer (20). A detector (28), of either Schottky or heterojunction/hybrid type, has a photoconducing polymer layer (64) or adjacent conducting polymer (76) and semiconductor (78) layers where at least one is photoconducting.(FR) L'invention se rapporte à un détecteur optique (10) comprenant une source de lumière (18) polymère et/ou un détecteur de lumière (28) polymère. Une source électroluminescente (18) présente une couche polymère conductrice (20) ou, selon une variante, une couche de phosphore (20). Un détecteur (28) du type Schottky ou hybride/à hétérojonction, comprend une couche polymère photoconductrice (64), ou une couche polymère conductrice (76) et une couche semi-conductrice (78) adjacentes, dont au moins une est photoconductrice.
• Cationic ring-opening polymerization of carbazolyl-containing epoxy monomers by triphenyl carbenium salts as thermal- and photolatent initiators
  作者：Ruta Lazauskaite、Maryte Daskeviciene、Vytautas Getautis、Juozas V. Grazulevicius

  DOI：10.1007/s00706-008-0090-6

  日期：2009.5

  ]-9H-carbazole, as well as a composition of 3,6-dibromo-9-(oxiran-2-ylmethyl)-9H-carbazole with 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexane carboxylate were investigated in bulk using triphenyl carbenium salts having anions such as BF4 −, SnCl5 −, and SbCl6 −. Dark polymerizations of the carbazolyl monomers in the presence of the initiators are studied. These photoinduced polymerization reactions

  摘要带有咔唑部分，9- [3-（烯丙氧基）-2-（环氧乙烷-2-基甲氧基）丙基] -9 H-咔唑，9- [3-甲氧基-2-（环氧乙烷-）的各种环氧单体的光引发阳离子聚合2-基甲氧基）丙基] -9 H-咔唑，9- [2-（环氧乙烷-2-基甲氧基）乙基] -9 H-咔唑以及3,6-二溴-9-（环氧乙烷-2）的组成基甲基）-9 ħ与3,4-环氧环己基-3,4-环氧环己烷羧酸酯-咔唑进行批量使用具有阴离子如BF三苯基碳盐调查4 - ，的SnCl 5 - ，和的SbCl 6 -。研究了在引发剂存在下咔唑基单体的黑暗聚合。这些光诱导的聚合反应给出聚合度为4-22的低聚物。讨论了光引发剂阴离子和聚合时间对聚合反应的影响。 图形概要