lithium 10-azaacepentalenide | 847849-59-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: lithium 10-azaacepentalenide
• CAS: 847849-59-6
• 化学式: C₉H₆LiN
• 分子量: 135.094
• InChiKey: RASMTBRCHPWJAO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  lithium 10-azaacepentalenide 在 rhodium on alumina 氢气 作用下， 生成 (2aS,4aS,6aR)-2a-Benzyl-octahydro-6b-aza-cyclopenta[cd]pentalene
  参考文献：
  名称：

  The Azaacepentalenide Anion:  A New Aromatic, Bowl-Shaped Heterocycle

  摘要：

  The bowl-shaped aromatic azaacepentalenide anion and its perchloro analogue were derived from 10-azatriquinacene and 2,3,5,6,8,9-hexachloro-10-azatriquinacene via the N-oxides. Spectroscopic and computational studies, as well as chemical derivitization experiments, were used to confirm the structural assignments.

  DOI：

  10.1021/ja043593c
• 作为产物：
  描述：

  10-azatriquinacene-N-oxide 在 正丁基锂 作用下， 以 氘代四氢呋喃 、 正己烷 为溶剂， 反应 2.0h， 生成 lithium 10-azaacepentalenide
  参考文献：
  名称：

  The Azaacepentalenide Anion:  A New Aromatic, Bowl-Shaped Heterocycle

  摘要：

  The bowl-shaped aromatic azaacepentalenide anion and its perchloro analogue were derived from 10-azatriquinacene and 2,3,5,6,8,9-hexachloro-10-azatriquinacene via the N-oxides. Spectroscopic and computational studies, as well as chemical derivitization experiments, were used to confirm the structural assignments.

  DOI：

  10.1021/ja043593c