氰甲基二苯基氨基甲酸二硫酯 | 1366396-40-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 氰甲基二苯基氨基甲酸二硫酯
• 英文名称: N,N-diphenyldithiocarbamic acid cyanomethyl ester
• 英文别名: diphenyldithiocarbamic acid cyanomethyl ester；Cyanomethyl N,N-Diphenylamine Carbodithioate；S-cyanomethyl-N,N-diphenylcarbamodithioate；S-cyanomethyl-N,N-diphenyldithiocarbamate；cyanomethyl N,N-diphenyldithiocarbamate；cyanomethyl diphenylcarbamodithioate；cyanomethyl N,N-diphenylcarbamodithioate
• CAS: 1366396-40-8
• 化学式: C₁₅H₁₂N₂S₂
• 分子量: 284.406
• InChiKey: MYKFCCXEAFCDMK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  84.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二苯胺 在 sodium hydride 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 生成 氰甲基二苯基氨基甲酸二硫酯
  参考文献：
  名称：

  环境条件下氯三氟乙烯和乙烯基醚的光有机催化可逆失活交替共聚：轻松获得主链氟化共聚物

  摘要：

  几十年来，含氟聚合物得到了广泛的应用。相当多的努力集中在扩大对主链氟化聚合物的访问。与之前在高温和高压金属容器中进行的气态氟乙烯聚合相比，我们在此报告了三氟氯乙烯 (CTFE) 和乙烯基醚 (VE) 的光有机催化可逆失活自由基交替共聚的发展。通过暴露于 LED 光照射室温和环境压力。该方法能够合成各种具有低 Ð 和高链端保真度的氟化交替共聚物，允许在“开”和“关”状态之间反复切换共聚，制备氟化嵌段交替共聚物，

  DOI：

  10.1021/jacs.0c01016

文献信息

• Polymerizable sulfonamide compounds and polymers thereof
  申请人：Massachusetts Institute of Technology

  公开号：US11155674B2

  公开（公告）日：2021-10-26

  Methods, compositions, reagents, and systems that allow for the preparation and utilization of sulfonamide salt polymer electrolytes are disclosed herein. Methods and reagents to prepare sulfonamide salt monomers are also disclosed herein. The sulfonamide salt polymer electrolytes can be used as components in energy storage devices, conductive materials, electrochemical cells, gels, adhesives, and drug delivery vehicles.

  本文公开了允许制备和利用磺胺盐聚合物电解质的方法、组合物、试剂和系统。本文还公开了制备磺胺盐单体的方法和试剂。磺胺盐聚合物电解质可用作能量存储设备、导电材料、电化学电池、凝胶、粘合剂和药物输送载体中的组件。
• ALKENYL ETHER-VINYL ESTER COPOLYMER
  申请人：Maruzen Petrochemical Co., Ltd.

  公开号：EP3296333A1

  公开（公告）日：2018-03-21

  To provide a temperature responsive polymer that has an arbitrary LCST in a wide temperature range of from a low temperature range of body temperature or room temperature to a high temperature range of 80°C or more, and to provide a method capable of providing the polymer easily. An alkenyl ether-vinyl ester copolymer containing a repeating unit derived from a hydroxyl group-containing alkenyl ether represented by the formula (1), and a repeating unit derived from a vinyl ester represented by the formula (2), and exhibiting temperature responsiveness showing a change in hydrophilicity and hydrophobicity at a prescribed temperature as a critical point, and the alkenyl ether-vinyl ester copolymer that has a lower critical solution temperature to water of from 1°C to 99°C: wherein R1, R2, and R3 each independently represent a hydrogen atom or an alkyl group having a number of carbon atoms of from 1 to 4; R4 represents a linear or branched alkylene group having a number of carbon atoms of from 2 to 4; R5 represents an acyl group having a number of carbon atoms of from 1 to 20; and p represents an integer of from 1 to 3.

  提供一种温度响应性聚合物，该聚合物在从体温或室温的低温范围到 80°C 或更高的高温范围的宽温度范围内具有任意的 LCST，并提供一种能够轻松提供该聚合物的方法。一种烯基醚-乙烯基酯共聚物，其含有由式(1)表示的含羟基烯基醚衍生的重复单元和由式(2)表示的乙烯基酯衍生的重复单元，并具有温度响应性，在规定温度作为临界点时亲水性和疏水性发生变化，该烯基醚-乙烯基酯共聚物对水的临界溶液温度较低，为1℃至99℃： 其中 R1、R2 和 R3 各自独立地代表氢原子或碳原子数为 1 至 4 的烷基；R4 代表碳原子数为 2 至 4 的直链或支链亚烷基；R5 代表碳原子数为 1 至 20 的酰基；p 代表 1 至 3 的整数。
• FLUOROPOLYMER PRODUCTION METHOD AND FLUOROPOLYMER
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP3950725A1

  公开（公告）日：2022-02-09

  Provided are novel methods for producing a fluoropolymer. The disclosure relates to a method for producing a fluoropolymer by solution polymerization or dispersion polymerization, the method including: in the presence of an initiator, a chain transfer agent, and a solvent, (i) homopolymerizing tetrafluoroethylene; or (ii) randomly copolymerizing tetrafluoroethylene and at least one of a monomer represented by the following formula (1) or a monomer represented by the following formula (2), the chain transfer agent including at least one selected from the group consisting of dithioester compounds, dithiocarbamate compounds, trithiocarbonate compounds, and xanthate compounds, the fluoropolymer containing 50 to 100 mol% of a polymerized unit based on the tetrafluoroethylene,         the formula (1):     CF2=CR1R2 wherein R1 is H or F; R2 is -Cl, -Ra, -COORb, -OCORc, -CONRd2, -CN, -CORe, or -Rfa; Ra, Rb, Rc, Rd, and Re are the same as or different from each other and are each H or a substituent; Rfa is the same as or different from each other and is an optionally substituted fluorine-containing alkyl group, an optionally substituted fluorine-containing vinyl group, or an optionally substituted fluorine-containing alkoxy group, each group optionally containing an oxygen atom between carbon atoms; and R1 and R2 optionally bind to each other to form a ring,         the formula (2):     CH2=CR3R4 wherein R3 is Rg, CF3, or F; R4 is -Cl, -Rh, -COORi, -OCORj, -CONRk2, -CN, -CORm, or Rfc; Rg and Rh are the same as or different from each other and are each H, an optionally substituted hydrocarbon group, or an optionally substituted heterocyclic group; Ri, Rj, Rk, and Rm are the same as or different from each other and are each H or a substituent; Rfc is the same as or different from each other and is an optionally substituted fluorine-containing alkyl group, an optionally substituted fluorine-containing vinyl group, or an optionally substituted fluorine-containing alkoxy group, each group optionally containing an oxygen atom between carbon atoms; and R3 and R4 optionally bind to each other to form a ring.

  本发明提供了生产含氟聚合物的新方法。本公开涉及一种通过溶液聚合或分散聚合生产含氟聚合物的方法，该方法包括：在引发剂、链转移剂和溶剂存在的情况下，(i) 均聚四氟乙烯；或 (ii) 无规共聚四氟乙烯和下式 (1) 所代表的单体或下式 (2) 所代表的单体中的至少一种、 链转移剂包括至少一种选自二硫代酯化合物、二硫代氨基甲酸酯化合物、三硫代碳酸盐化合物和黄原酸盐化合物组成的组，含氟聚合物含有基于四氟乙烯的 50 至 100 摩尔%的聚合单元、 式（1）：CF2=CR1R2 其中 R1 是 H 或 F；R2 是 -Cl、-Ra、-COORb、-OCORc、-CONRd2、-CN、-CORe 或 -Rfa；Ra、Rb、Rc、Rd 和 Re 彼此相同或不同，并且各自是 H 或取代基；Rfa彼此相同或不同，是任选取代的含氟烷基、任选取代的含氟乙烯基或任选取代的含氟烷氧基，每个基团在碳原子之间任选含有一个氧原子；以及 R1 和 R2 任选彼此结合形成一个环、 式 (2)：CH2=CR3R4 其中 R3 是 Rg、CF3 或 F；R4 是 -Cl、-Rh、-COORi、-OCORj、-CONRk2、-CN、-CORm 或 Rfc；Rg 和 Rh 彼此相同或不同，各自是 H、任选取代的烃基或任选取代的杂环基；Ri、Rj、Rk 和 Rm 彼此相同或不同，各自是 H 或取代基；Rfc 彼此相同或不同，是任选取代的含氟烷基、任选取代的含氟乙烯基或任选取代的含氟烷氧基，每个基团在碳原子之间任选含有一个氧原子；以及 R3 和 R4 任选彼此结合形成一个环。
• Method for producing alkenyl ether polymer
  申请人：Maruzen Petrochemical Co., Ltd.

  公开号：US10370478B2

  公开（公告）日：2019-08-06

  To provide a method for producing a polymer that is capable of providing an alkenyl ether polymer having a molecular weight, a molecular weight distribution, and a composition that are controlled, with a vinyl ether having a hydroxyl group, and a block copolymer thereof. To provide a polymer obtained by the method as a macro chain transfer agent capable of performing reversible addition fragmentation chain transfer polymerization. Livingness can be imparted to radical polymerization of a hydroxyl group-containing vinyl ether by performing the radical polymerization in the presence of a particular RAFT agent and a radical polymerization initiator, and a block copolymer with another radically polymerizable vinyl monomer can be obtained by using the resulting living polymer as a macro chain transfer agent capable of performing reversible addition fragmentation chain transfer polymerization.

  提供一种生产聚合物的方法，该方法能够提供一种分子量、分子量分布和组成均可控 制的烯基醚聚合物，其中含有一个羟基的乙烯基醚及其嵌段共聚物。提供一种通过该方法获得的聚合物，作为大分子链转移剂，能够进行可逆加成片段链转移聚合。通过在特定 RAFT 剂和自由基聚合引发剂存在下进行自由基聚合，可使含羟基的乙烯基醚的自由基聚合具有活 性，并通过将所得活聚合物用作能够进行可逆加成片段链转移聚合的大分子链转移剂，可获得与另一种可进行自由基聚合的乙烯基单体的嵌段共聚物。
• Alkenyl ether-vinyl ester copolymer
  申请人：Maruzen Petrochemical Co., Ltd.

  公开号：US10570232B2

  公开（公告）日：2020-02-25

  An alkenyl ether-vinyl ester copolymer contains a repeating unit derived from a hydroxyl group-containing alkenyl ether represented by the following formula (1), and a repeating unit derived from a vinyl ester represented by the following formula (2): where R1, R2, and R3 each independently represents a hydrogen atom or an alkyl group having from 1 to 4 carbon atoms; R4 represents a linear or branched alkylene group having from 2 to 4 carbon atoms; R5 represents an acyl group having from 1 to 20 carbon atoms; and p represents an integer of from 1 to 3. The alkenyl ether-vinyl ester copolymer exhibits temperature responsiveness showing a change in hydrophilicity and hydrophobicity at a prescribed temperature as a critical point and has a lower critical solution temperature to water of from 1° C. to 99° C.

  烯基醚-乙烯基酯共聚物包含由下式（1）表示的含羟基烯基醚衍生的重复单元和由下式（2）表示的乙烯基酯衍生的重复单元： 其中 R1、R2 和 R3 各自独立地代表氢原子或具有 1 至 4 个碳原子的烷基；R4 代表具有 2 至 4 个碳原子的直链或支链亚烷基；R5 代表具有 1 至 20 个碳原子的酰基；p 代表 1 至 3 的整数。烯基醚-乙烯基酯共聚物具有温度响应性，在规定温度作为临界点时，亲水性和疏水性会发生变化，与水的下临界溶液温度为 1 摄氏度至 99 摄氏度。