[Cu(4-(2-Hydroxy-phenyl)-3-aza-1-amino-3-butene(1-))(SCN)] | 507479-37-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Cu(4-(2-Hydroxy-phenyl)-3-aza-1-amino-3-butene(1-))(SCN)]
• 英文别名: copper;2-(2-aminoethyliminomethyl)phenolate;thiocyanate
• CAS: 507479-37-0
• 化学式: C₁₀H₁₁CuN₃OS
• 分子量: 284.829
• InChiKey: LJDGRHNUPGKIET-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium thioacyanate 、 copper(II) choride dihydrate 、 2-(2-aminomethyl)iminomethylphenol 以 乙醇 为溶剂， 以60%的产率得到[Cu(4-(2-Hydroxy-phenyl)-3-aza-1-amino-3-butene(1-))(SCN)]
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF SOME THIOCYANATO COMPLEXES OF Ni(II), Cu(II), Pd(II), Pt(II), Au(III), Ti(III), AND V(IV) CONTAINING A TRIDENTATE SCHIFF BASE LIGAND

  摘要：

  A tridentate ligand HL having a ONN donor sequence has been synthesised by the condensation of ethylenediamine with salicylaldehyde. The ligand undergoes deprotonation during complexation. and forms complexes of the compositions, [M(L)(SCN)], [M = Ni(II), Cu(II), Pd(II) and Pt(II), L = deprotonated Schiff base], K[Ti(L)(SCN)(3)], [Au(L)-(SCN)]Cl and K[V(O)(L)(SCN)(2)]. These complexes were,characterized on the basis of elemental analyses, conductivity and magnetic measurements, NMR, infrared and electronic spectral studies. The magnetic and spectral data are consistent with square-planar stereochemistry for the Ni(II), Cu(II), Pd(II), Pt(II) and Au(III) complexes while the Ti(III) and V(IV) complexes are octahedral in nature.

  DOI：

  10.1081/sim-120016468