[N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Cu] | 156836-89-4

• 分子结构分类: 有机化合物
• 英文名称: [N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Cu]
• 英文别名: [N,N'-Phenylen-bis(3-formyl-5-tert.-butyl-salicylaldimin)Cu]
• CAS: 156836-89-4
• 化学式: C₃₀H₃₀CuN₂O₄
• 分子量: 546.125
• InChiKey: PVPPXWUCHRJJDB-KFZCUDJASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 [1,1’-联萘]-2,2’-二胺 、 [N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Cu] 以 乙醇 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  与手性大环席夫碱型配体的双核铜 (II) 配合物：合成和结构

  摘要：

  The synthesis and properties of four chiral, dinuclear, macrocyclic, cationic copper(II) complexes, [Cu-2(L-m,L-n)](2+) (1-4), are described. The two symmetrical compounds [Cu-2(L-2,L-2)][ClO4](2) (1 and 2) were synthesized in a one-step reaction from 2,6-diformyl-4-tert.-butylphenol, copper(II)-perchlorate and the chiral diamine (1S,2S)-1,2-diphenylethylenediamine (synthesis of 1) and (1R,2R)-1,2-diaminocyclohexane (synthesis of 2), respectively. For the synthesis of the two unsymmetrical compounds [Cu-2(L-Ph,L-n)]-ClO4](2) (3 and 4) the mononuclear, neutral copper(II) complex [CuLPh] (5) [synthesized from 2,6-diformyl-4-tert.-butyl-phenol, copper(II)-acetate and 1,2-phenylenediamine] was reacted with (1R,2R)-1,2-diaminocyclohexane (synthesis of 3) and (8)-1,1'-binaphthyl-2,2'-diamine (synthesis of 4), respectively. The structures of the two unsymmetrical copper(II) compounds (3 and 4) were determined by X-ray diffraction.

  DOI：

  10.1002/1521-3749(200102)627:2<238::aid-zaac238>3.0.co;2-4
• 作为产物：
  描述：

  4-叔丁基-2,6-二甲酰基苯酚 、 copper diacetate 、 间苯二胺 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 以89%的产率得到[N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Cu]
  参考文献：
  名称：

  摘要：

  The synthesis and properties of nickel(II), copper(II), and palladium(II) complexes, [MLPh] (3; L-Ph = N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)), are described. These neutral mononuclear complexes react with metal(II) perchlorate and 1,3-propylenediamine to form heterodinuclear, macrocyclic, cationic complexes of the type [MM'(L-Ph,L-3)](2+) (4; M = Ni, Cu, Pd; M' = Co, Cu, Zn). The structures of the five new compounds [NiCo(L-Ph,L-3)](ClO4)(2), [NiCu(L-Ph,L-3)](ClO4)(2), [CuCu(L-Ph,L-3)](ClO4)(2), [CuZn(L-Ph,L-3)](ClO4)(2), and [PdCu(L-Ph,L-3)](ClO4)(2) were determined by X-ray diffraction.

  DOI：

  10.1002/1521-3749(200009)626:9<1934::aid-zaac1934>3.0.co;2-g

文献信息

• Brychcy, Klaus; Jens, Klaus-J.; Tilset, Mats, Chemische Berichte, 1994, vol. 127, # 6, p. 991 - 996
  作者：Brychcy, Klaus、Jens, Klaus-J.、Tilset, Mats、Behrens, Ulrich

  DOI：——

  日期：——