tris[(4-aminophenoxy)phenyl]phosphine oxide | 1458617-90-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris[(4-aminophenoxy)phenyl]phosphine oxide
• 英文别名: 4,4',4''-(4,4',4''-phosphinetriyltris(benzene-4,1-diyl)tris(oxy))trianiline；TAPO；4-[4-Bis[4-(4-aminophenoxy)phenyl]phosphorylphenoxy]aniline；4-[4-bis[4-(4-aminophenoxy)phenyl]phosphorylphenoxy]aniline
• CAS: 1458617-90-7
• 化学式: C₃₆H₃₀N₃O₄P
• 分子量: 599.626
• InChiKey: RUPNHWRGFFHEPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  44
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  123
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  三(4-羟基苯基)氧化膦 在 5%-palladium/activated carbon 、 氢气 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 20.0~100.0 ℃ 、413.7 kPa 条件下， 反应 72.0h， 生成 tris[(4-aminophenoxy)phenyl]phosphine oxide
  参考文献：
  名称：

  Multifunctional crosslinkers for shape-memory polyimides, polyamides and poly(amide-imides) and methods of making the same

  摘要：

  可用于制备具有形状记忆性能的交联聚酰亚胺、聚酰胺和聚（酰亚胺）聚合物和薄膜的多功能胺交联剂，以及制备这些材料的方法。

  公开号：

  US08546614B1

文献信息

• Compositions and articles made from branched polyetherimides
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US11286347B2

  公开（公告）日：2022-03-29

  A branched polyimide of the formula (I) wherein G is a group having a valence of t, present in an amount of 0.01 to 10 mol %, or 0.05 to 5 mol %, or 0.1 to 4 mol %, or 0.1 to 3 mol %, each of Q, M, D, V, and R are as defined herein, q is 0 or 1, m is 0 or 1, d is 0 or 1, p is 1 or 2, t is 2 to 6, preferably 2 to 4, and each n is independently the same or different, and is 1 to 1,000, provided that the total of all values of n is greater than 4, wherein the branched polyimide has a zero-shear viscosity in a range from 500 to 15,000 Pa·s, a rheology ratio of 1.1 to 5, and a strain hardening ratio of 1 to 6.

  一种式(I)的支化聚酰亚胺 其中 G 是价数为 t 的基团，其含量为 0.01 至 10 摩尔 %，或 0.05 至 5 摩尔 %，或 0.1 至 4 摩尔 %，或 0.1至3摩尔％，Q、M、D、V和R各自如本文所定义，q为0或1，m为0或1，d为0或1，p为1或2，t为2至6，优选2至4，n各自独立地相同或不同，且为1至1,000，条件是所有n值的总和大于4，其中支化聚酰亚胺的零剪切粘度范围为500至15,000 Pa-s，流变比为1.1至5，应变硬化率为1至6。
• Linear and branched polyimide composition
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US11377521B2

  公开（公告）日：2022-07-05

  A polyimide composition includes 1 to 99 weight percent, preferably 70 to 99 weight percent, more preferably 75 to 95 weight percent of a first polyimide; and 1 to 99 weight percent, preferably 1 to 30 weight percent, more preferably 2 to 25 weight percent of a second polyimide, wherein the first polyimide and the second polyimide are different, and wherein the polyimide composition has a melt flow rate that is greater than a melt flow rate of the first polyimide and less than a melt flow rate of the second polyimide; an apparent viscosity that is less than an apparent viscosity of the first polyimide and less than an apparent viscosity of the second polyimide; and a notched Izod impact strength that is greater than a notched Izod impact strength of the first polyimide and greater than a notched Izod impact strength of the second polyimide.

  一种聚酰亚胺组合物包括 1 至 99 重量百分率，优选 70 至 99 重量百分率，更优选 75 至 95 重量百分率的第一种聚酰亚胺；以及 1 至 99 重量百分率，优选 1 至 30 重量百分率，更优选 2 至 25 重量百分率的第二种聚酰亚胺，其中第一种聚酰亚胺和第二种聚酰亚胺是不同的，且聚酰亚胺组合物的熔体流动速率大于第一种聚酰亚胺的熔体流动速率，小于第二种聚酰亚胺的熔体流动速率；表观粘度小于第一种聚酰亚胺的表观粘度，小于第二种聚酰亚胺的表观粘度；以及缺口伊佐德冲击强度大于第一种聚酰亚胺的缺口伊佐德冲击强度，大于第二种聚酰亚胺的缺口伊佐德冲击强度。
• POLYIMIDE AND POLYETHERIMIDE FROM METAL CONTAINING OLIGOMERS
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US20190211153A1

  公开（公告）日：2019-07-11

  A polyimide oligomer of the formula wherein G is a group having a valence of t, each R is independently a C 1-30 divalent bridging group, a C 1-20 alkylene-X, or a C 6-30 arylene-X wherein —X is —O-M′, —C(O)O-M′, —OC(O)O-M′, —S-M′, —S(O) 2 -M′, —S(O) 3 -M′, —OS(O) 3 -M′, or —OP(O) 3 -M′ wherein each M′ is independently Li, Na, K, Cs, Mg, Ca, Sr, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, In, Ge, Sn, Pb, As, or Sb, provided that at least one R is C 1-20 alkylene-X or C 6-30 arylene-X, q is 0 or 1, m is 0 or 1, d is 0 or 1, p is 1 or 2, t is 1 to 6, and each n is independently 1 to 1,000, the total of all values of n is greater than 4, the polyimide oligomer is thermoplastic, and Q, M, D, and V are as provided herein.
• LINEAR AND BRANCHED POLYIMIDE COMPOSITION
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US20190315963A1

  公开（公告）日：2019-10-17

  A polyimide composition includes 1 to 99 weight percent, preferably 70 to 99 weight percent, more preferably 75 to 95 weight percent of a first polyimide; and 1 to 99 weight percent, preferably 1 to 30 weight percent, more preferably 2 to 25 weight percent of a second polyimide, wherein the first polyimide and the second polyimide are different, and wherein the polyimide composition has a melt flow rate that is greater than a melt flow rate of the first polyimide and less than a melt flow rate of the second polyimide; an apparent viscosity that is less than an apparent viscosity of the first polyimide and less than an apparent viscosity of the second polyimide; and a notched Izod impact strength that is greater than a notched Izod impact strength of the first polyimide and greater than a notched Izod impact strength of the second polyimide.
• BRANCHED POLYIMIDE COMPOSITIONS, METHOD OF MANUFACTURE, AND USES THEREOF
  申请人：SABIC GLOBAL TECHNOLOGIES B.V.

  公开号：US20200115501A1

  公开（公告）日：2020-04-16

  A branched polyimide of the formula (I) wherein G is a group having a valence of t present in an amount 0.01 to 20 mol %, each Q is independently the same or different, and is a divalent C 1-60 hydrocarbon group, each M is independently the same or different, and is —O—, —C(O)—, —OC(O)—, —OC(O)O—, —NHC(O), —(O)CNH—, —S—, —S(O)—, or —S(O) 2 —, D is a phenylene, each V is independently the same or different, and is a tetravalent C 4-40 hydrocarbon group, each R is independently the same or different, and is a C 1-20 divalent hydrocarbon group, q is 0 or 1, m is 0 or 1, d is 0 or 1, p is 1 or 2, t is 2 to 6, and each n is independently the same or different, and is 1 to 1,000, provided that the total of all values of n is greater than 4.