[Cu3(N-(3-tert-butylbenzoyl)-5-bromosalicylhydrazide-3H)2(pyridine)2] | 1132810-43-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Cu3(N-(3-tert-butylbenzoyl)-5-bromosalicylhydrazide-3H)2(pyridine)2]
• CAS: 1132810-43-5
• 化学式: C₄₆H₄₂Br₂Cu₃N₆O₆
• 分子量: 1125.32
• InChiKey: MGOOPSCDDMXXSV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 N-(3-tert-butylbenzoyl)-bromosalicylhydrazide 、 copper(II) acetate monohydrate 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 以76.5%的产率得到[Cu3(N-(3-tert-butylbenzoyl)-5-bromosalicylhydrazide-3H)2(pyridine)2]
  参考文献：
  名称：

  Metal coordination architectures of N-acyl-salicylhydrazides: The effect of metal ions and steric repulsion of ligands to their structures of polynuclear metal complexes

  摘要：

  Three polynuclear transition metal complexes [Mn(8)(DMF)(8)(L1)(8)] center dot 4DMF (1), [Mn(6)(DMF)(6)(L2)(6)] center dot [Mn(6)(DMF)(4)(H(2)O)(2)(L2)(6)] center dot 2DMF (2), [Cu(3)(L3)(2)(py)(2)] (3) of the pentadentate ligands N-acyl-salicylhydrazides were synthesized and characterized, their crystal structures were investigated. The oxidation state and properties of the central metal ions are important in crystal structure formation, trivalent Mn(III) ion which easily form stable octahedral coordination metallamacrocycle complexes, metallacrowns 1 and 2 were obtained; while bivalent Cu(II) ion is easier to form square planar, trinuclear complexes 3 was obtained. The steric effect of the N-acyl side chains also plays an important role in the structures of these polynuclear complexes. The magnetic property of 1 was also investigated. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.055